Citation: LI Zhanguo, FAN Sida, ZHANG Liang, ZHANG Peipei, SUN Lijing, YIN Li, ZHANG Jidong, WANG Lijuan. Preparation of Large-size Graphene Oxide Films Based on Iron(Ⅲ) Chloride Catalysis[J]. Chinese Journal of Applied Chemistry, ;2018, 35(2): 232-238. doi: 10.11944/j.issn.1000-0518.2018.02.170083 shu

Preparation of Large-size Graphene Oxide Films Based on Iron(Ⅲ) Chloride Catalysis

LI Zhanguo ^a ,
FAN Sida ^a,b ,
ZHANG Liang ^b ,
ZHANG Peipei ^a,b ,
SUN Lijing ^b ,
YIN Li ^b ,
ZHANG Jidong ^c ,
WANG Lijuan ^b,,

a.
School of Electro-Optical Engineering, Changchun University of Science and Technology, Changchun 130022, China
b.
School of Chemical Engineering, Changchun University of Technology, Changchun 130012, China
c.
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Corresponding author: WANG Lijuan, wlj15@163.com
Received Date: 24 March 2017
Revised Date: 8 May 2017
Accepted Date: 26 June 2017

Fund Project: the Scientific Research Foundation of Education Department of Jilin Province 2016326the Scientific Research Foundation of Education Department of Jilin Province JJKH20170556KJthe Key Program for Science and Technology Development of Jilin Province of China 20170204014SFthe National Natural Science Foundation of China 21403016Supported by the National Natural Science Foundation of China(No.21403016), the Scientific Research Foundation of Education Department of Jilin Province(No.2016326, No.JJKH20170556KJ), the Key Program for Science and Technology Development of Jilin Province of China(No.20170204014SF)

Figures(6)

In order to obtain large-area graphene oxide(L-GO) films, a series of FeCl₃-catalyzed L-GO films are prepared. The surface morphology and structure of L-GO films synthesized with various temperatures and times are studied by atomic force microscope(AFM), polarizing microscope(POM), Fourier transform infrared spectrometer(FTIR), and X-ray diffraction(XRD). The sheet domain area of FeCl₃-catalyzed L-GO films is 10 μm×10 μm, which increases about four times in contrast to that of GO films prepared without catalyst. By further analysis of FTIR and XRD, the formation of L-GO domains can be attributed to the new connections of the hydroxyl, carboxyl, and carbonyl groups in graphene oxide under FeCl₃ catalysis. Thus, a formation model of FeCl₃-catalyzed L-GO films is proposed, which provides a new way for the preparation of large area graphene oxide films.
- iron chloride,
- catalyst,
- graphene oxide sheet,
- large-size thin film,
- surface morphology,
- Fourier transform infrared spectroscopy
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