Citation: SUN Qi, WANG Liqiu, LIU Yang, GUO Chenxiao, WANG Pengjun, LIU Xuelong, ZHANG Xiaobo, ZHENG Lihui, LIU Liping. Preparation and Properties of Near Infrared Polyvinyl Alcohol Fluorescent Polymer Materials[J]. Chinese Journal of Applied Chemistry, ;2018, 35(1): 53-59. doi: 10.11944/j.issn.1000-0518.2018.01.170344 shu

Preparation and Properties of Near Infrared Polyvinyl Alcohol Fluorescent Polymer Materials

SUN Qi ^a,b ,
WANG Liqiu ^a,, ,
LIU Yang ^a ,
GUO Chenxiao ^a ,
WANG Pengjun ^a ,
LIU Xuelong ^a ,
ZHANG Xiaobo ^a ,
ZHENG Lihui ^a ,
LIU Liping ^c

a.
College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao, Hebei 066004, China
b.
Jiangxi Kingan Hi-Tech Co., Ltd. Nanchang 330508, China
c.
Qiqihar Education and Teaching Research Institute, Qiqihar, Heilongjiang 161005, China

Corresponding author: WANG Liqiu, liqiuwang@tom.com
Received Date: 19 September 2017
Revised Date: 24 October 2017
Accepted Date: 30 October 2017

Fund Project: Supported by Hebei Natural Science Foundation(No.B2015203259)Hebei Natural Science Foundation B2015203259

Figures(8)

Near-infrared fluorescence squaraine/polyvinyl alcohol(PVA) binary and squaraine/hydrophilic graphene/PVA ternary polymers with stronger fluorescence(660~665 nm) intensity, photostability and thermostability were designed and synthesized from a squaraine dye, water soluble graphene and PVA. Compared to those in water, the maximum UV-Vis absorption and fluorescence wavelengths of the squaraine in PVA showed red shifts, and the fluorescence intensity and photostability were significantly enhanced. The presence of the graphene improved the photostability and thermostability of the material.
- near infrared fluorescence polymer materials,
- polyvinyl alcohol,
- modification and synthesis,
- squaraine dye,
- hydrophilic grapheme
1. [1]
  Takizawa K, Wakita J, Kakiage M. Molecular Aggregation Structures of Polyimide Films at Very High Pressure Analyzed by Synchrotron Wide-angle X-Ray Diffraction[J]. Macromolecules, 2010,43(5):2115-2117. doi: 10.1021/ma902662d
2. [2]
  Evanoff D D, Carroll J B, Roeder R D. Poly(methyl methacrylate) Copolymers Containing Pendant Carbazole and Oxadiazole Moieties for Applications in Single-Layer Organic Light Emitting Devices[J]. J Polym Sci Part A Polym Chem, 2008,46(23):7882-7897. doi: 10.1002/pola.v46:23
3. [3]
  Lee T S, Yang C D, Park W H. Synthesis and Electrostatic Multilayer Assembly of an Acridine-Containing Polymer with Properties of an Optical Sensor[J]. Macromol Rapid Commun, 2000,21(14):951-955. doi: 10.1002/(ISSN)1521-3927
4. [4]
  Niu C G, Li Z Z. Covalently Immobilized Aminonaphthalimide as Fluorescent Carrier for the Preparation of Optical Sensors[J]. Anal Bioanal Chem, 2002,372(4):519-524. doi: 10.1007/s00216-001-1141-6
5. [5]
  Lee S L, Lin N T, Liao W C. Oligomeric Tectonics:Supramolecular Assembly of Double-Stranded Oligobisnorbornene Through Pi-Pi Stacking[J]. Chemistry, 2009,15(43):11594-11600. doi: 10.1002/chem.200901634
6. [6]
  HUANG Cuihua, XU Weijian. Developments in Application Research of Fluorescent Polymer[J]. Appl Chem Ind, 2001,30(1):9-12.
7. [7]
  Novoselov K S, Geim A K, Morozov S V. Two-Dimensional Gas of Massless Dirac Fermions in Graphene[J]. Nature, 2005,438(7065):197-200. doi: 10.1038/nature04233
8. [8]
  Yamada A, Hiruta Y, Wang J. Design of Environmentally Responsive Fluorescent Polymer Probes for Cellular Imaging[J]. Biomacromolecules, 2015,16(8):2356-2362. doi: 10.1021/acs.biomac.5b00591
9. [9]
  Wang D, Miyamoto R, Shiraishi Y. BODIPY-Conjugated Thermoresponsive Copolymer as a Fluorescent Thermometer Based on Polymer Microviscosity[J]. Langmuir, 2009,25(22):13176-13182. doi: 10.1021/la901860x
10. [10]
  PAN Yuyu. Preparation and Properties of Silicon-Doped Eu³⁺-PMMA Fluorescent Materials by Sol-Gel[D]. Yangzhou University, 2014(in Chinese).
11. [11]
  Gonzalez J S, Maiolo A S, Hoppe C E. Composite Gels Based on Poly(vinyl alcohol) for Biomedical Uses[J]. Procedia Mater Sci, 2012,1(1):483-490.
12. [12]
  Annabi N, Tamayol A, Uquillas J A. 25th Anniversary Article:Rational Design and Applications of Hydrogels in Regenerative Medicine[J]. Adv Mater, 2014,26(1):85-124. doi: 10.1002/adma.201303233
13. [13]
  Liu G C, Song Y, Wang J M. Effects of Nanoclay Type on the Physical and Antimicrobial Properties of PVOH-based Nanocomposite Films[J]. LWT-Food Sci Technol, 2014,57(2):562-568. doi: 10.1016/j.lwt.2014.01.009
14. [14]
  Heiba Z K, Mohamed M B, Imam N G. Optical and Electrical Properties of Quantum Composite of Polyvinyl Alcohol Matrix with CdSe Quantum Dots[J]. Colloid Polym Sci, 2016,294(2):357-365. doi: 10.1007/s00396-015-3793-3
15. [15]
  Goutayer M, Navarro G F Y, Texier N I. Fluorescent Emulsion of Indocyanine Green:CA, US9289517[P]. 2016.
16. [16]
  Guo M, Diao P, Ren Y J. Photoelectrochemical Studies of Nanocrystalline TiO₂ Co-Sensitized by Novel Cyanine Dyes[J]. Sol Energy Mater Sol Cells, 2005,88(1):23-35. doi: 10.1016/j.solmat.2004.10.003
17. [17]
  Zhou X, Zhou J. Improving the Signal Sensitivity and Photostability of DNA Hybridizations on Microarrays by Using Dye-Doped Core-Shell Silica Nanoparticles[J]. Anal Chem, 2004,76(18):5302-5312. doi: 10.1021/ac049472c
18. [18]
  Guo D, Zhu Y. Cohesive-Shear-Lag Modeling of Interfacial Stress Transfer Between a Monolayer Graphene and a Polymer Substrate[J]. J Appl Mech, 2015,82(3)031005. doi: 10.1115/1.4029635
19. [19]
  Navarro J R, Lerouge F, Micouin G. Plasmonic Bipyramids for Fluorescence Enhancement and Protection Against Photobleaching[J]. Nanoscale, 2014,6(10):5138-5145. doi: 10.1039/c3nr06425e
20. [20]
  Wang L Q, Wang P J, Liu Y. Near-infrared Indocyanine Materials for Bioanalysis and Nano-TiO₂, Photoanodes of Solar Cell[J]. J Nanomater, 2013,2013(1):8-13.
21. [21]
  Marcano D C, Kosynkin D V, Berlin J M. Improved Synthesis of Graphene Oxide[J]. ACS Nano, 2010,4(8):4806-4814. doi: 10.1021/nn1006368
22. [22]
  Wang L Q, Wang P J, Liu Y. Effects of Phenylhydrazine-4-sulfonic Acid on the Reduction of GO and Preparation of Hydrophilic Graphene with Broad pH Stability and Antioxidant Activity[J]. RSC Adv, 2015,5(48):38696-38705. doi: 10.1039/C4RA15454A
1. [1]
  Anbang Du , Yuanfan Wang , Zhihong Wei , Dongxu Zhang , Li Li , Weiqing Yang , Qianlu Sun , Lili Zhao , Weigao Xu , Yuxi Tian . Photothermal Microscopy of Graphene Flakes with Different Thicknesses. Acta Physico-Chimica Sinica, 2024, 40(5): 2304027-0. doi: 10.3866/PKU.WHXB202304027
2. [2]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
3. [3]
  Chaolin Mi , Yuying Qin , Xinli Huang , Yijie Luo , Zhiwei Zhang , Chengxiang Wang , Yuanchang Shi , Longwei Yin , Rutao Wang . Galvanic Replacement Synthesis of Graphene Coupled Amorphous Antimony Nanoparticles for High-Performance Sodium-Ion Capacitor. Acta Physico-Chimica Sinica, 2024, 40(5): 2306011-0. doi: 10.3866/PKU.WHXB202306011
4. [4]
  Tao Xu , Wei Sun , Tianci Kong , Jie Zhou , Yitai Qian . Stable Graphite Interface for Potassium Ion Battery Achieving Ultralong Cycling Performance. Acta Physico-Chimica Sinica, 2024, 40(2): 2303021-0. doi: 10.3866/PKU.WHXB202303021
5. [5]
  Ruonan Li , Shijie Liang , Yunhua Xu , Cuifen Zhang , Zheng Tang , Baiqiao Liu , Weiwei Li . Chlorine-Substituted Double-Cable Conjugated Polymers with Near-Infrared Absorption for Low Energy Loss Single-Component Organic Solar Cells. Acta Physico-Chimica Sinica, 2024, 40(8): 2307037-0. doi: 10.3866/PKU.WHXB202307037
6. [6]
  Rui Xu , Wei Li , Tianyi Li . Exploration of Teaching Reform in the Course of “Principles of Chemical Engineering” in the Polymer Materials and Engineering Major. University Chemistry, 2025, 40(4): 54-58. doi: 10.12461/PKU.DXHX202404081
7. [7]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368
8. [8]
  Qi Wang , Yicong Gao , Feng Lu , Quli Fan . Preparation and Performance Characterization of the Second Near-Infrared Phototheranostic Probe: A New Design and Teaching Practice of Polymer Chemistry Comprehensive Experiment. University Chemistry, 2024, 39(11): 342-349. doi: 10.12461/PKU.DXHX202404141
9. [9]
  Xuejun Lai , Anqiang Zhang , Tao Wang , Shuizhu Wu , Guangzhao Zhang . Construction and Practice of the First-Class Undergraduate Education Program for Polymer Materials and Engineering Major Students with “Solid Foundation, Strong Capability and High Potential”. University Chemistry, 2025, 40(4): 119-125. doi: 10.12461/PKU.DXHX202407012
10. [10]
  Yan Wang , Haolong Li , Chengji Zhao , Zheng Chen , Quan Lin , Yupeng Guo , Jianxin Mu , Kun Liu , Zhong-Yuan Lu , Junqi Sun . Construction Practice of the National First-Class Undergraduate Major in Polymer Materials and Engineering at Jilin University. University Chemistry, 2025, 40(4): 46-53. doi: 10.12461/PKU.DXHX202403083
11. [11]
  Tianqi Bai , Kun Huang , Fachen Liu , Ruochen Shi , Wencai Ren , Songfeng Pei , Peng Gao , Zhongfan Liu . Nanoscale Mechanism of Microstructure-Dependent Thermal Diffusivity in Thick Graphene Sheets. Acta Physico-Chimica Sinica, 2025, 41(3): 2404024-0. doi: 10.3866/PKU.WHXB202404024
12. [12]
  Yue Zhang , Bao Li , Lixin Wu . GO-Assisted Supramolecular Framework Membrane for High-Performance Separation of Nanosized Oil-in-Water Emulsions. Acta Physico-Chimica Sinica, 2024, 40(5): 2305038-0. doi: 10.3866/PKU.WHXB202305038
13. [13]
  Rui Gao , Ying Zhou , Yifan Hu , Siyuan Chen , Shouhong Xu , Qianfu Luo , Wenqing Zhang . Design, Synthesis and Performance Experiment of Novel Photoswitchable Hybrid Tetraarylethenes. University Chemistry, 2024, 39(5): 125-133. doi: 10.3866/PKU.DXHX202310050
14. [14]
  Lisha LEI , Wei YONG , Yiting CHENG , Yibo WANG , Wenchao HUANG , Junhuan ZHAO , Zhongjie ZHAI , Yangbin DING . Application of regenerated cellulose and reduced graphene oxide film in synergistic power generation from moisture electricity generation and Mg-air batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1151-1161. doi: 10.11862/CJIC.20240202
15. [15]
  Wenjun Yang , Qiaoling Tan , Wenjiao Xie , Xiaoyu Pan , Youyong Yuan . Construction and Characterization of Calcium Alginate Microparticle Drug Delivery System: A Novel Design and Teaching Practice in Polymer Experiments. University Chemistry, 2025, 40(3): 371-380. doi: 10.12461/PKU.DXHX202405150
16. [16]
  Kai Yang , Gehua Bi , Yong Zhang , Delin Jin , Ziwei Xu , Qian Wang , Lingbao Xing . Comprehensive Polymer Chemistry Experiment Design: Preparation and Characterization of Rigid Polyurethane Foam Materials. University Chemistry, 2024, 39(4): 206-212. doi: 10.3866/PKU.DXHX202308045
17. [17]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
18. [18]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
19. [19]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
20. [20]
  Yuhui Yang , Jintian Luo , Biao Zuo . A Teaching Approach to Polymer Surface and Interface in Undergraduate Polymer Physics Courses. University Chemistry, 2025, 40(4): 126-130. doi: 10.12461/PKU.DXHX202408056

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(1099)
HTML views(224)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142