Citation: XU Kerui, ZHONG Zhiming, XU Huidong, WANG Xuan, ZHAO Min, WU Chuande. Highly Efficient Aerobic Oxidation of Arylalkanes with a Biomimetic Catalyst Platform[J]. Chinese Journal of Applied Chemistry, ;2017, 34(9): 1079-1085. doi: 10.11944/j.issn.1000-0518.2017.09.170191 shu

Highly Efficient Aerobic Oxidation of Arylalkanes with a Biomimetic Catalyst Platform

State Key Laboratory of Silicon Materials, Department of Chemistry, Zhejiang University, Hangzhou 310027, China

Corresponding author: WU Chuande, cdwu@zju.edu.cn

^‡

Received Date: 2 June 2017
Revised Date: 26 June 2017
Accepted Date: 27 June 2017

Fund Project: Supported by the National Natural Science Foundation of China(No.21373180, No.21525312), the Fundamental Research Funds for the Central Universities(No.2017XZZX001-03A, No.2017FZA3007)the Fundamental Research Funds for the Central Universities 2017XZZX001-03Athe Fundamental Research Funds for the Central Universities 2017FZA3007the National Natural Science Foundation of China 21373180the National Natural Science Foundation of China 21525312

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It is a challenge to oxidize inert hydrocarbons with molecular oxygen, which can be easily realized by enzymes under mild conditions. Inspired by the catalytic mechanism of enzymes, we used the composite material CuPW₁₁@HKUST-1, consisting of encapsulated Keggin-type polyoxometalate[CuPW₁₁O₃₉]^5-(abbreviated as CuPW₁₁) in the pore space of metal-organic framework HKUST-1, as a redox catalyst, and N-hydroxyphthalimide(NHPI) as a co-catalyst, for the biomimetic aerobic oxidation of arylalkanes under mild conditions. The biomimetic system exhibits enzyme-like features of high efficiency and high selectivity in the aerobic oxidation of arylalkanes by imitating the structural features, active sites and catalytic mechanism of enzymes, in which up to 99% yield and 17700 turnover number(TON) have been realized in the aerobic oxidation reaction. This work offers a feasible pathway for highly efficient aerobic oxidation of inert organic molecules under mild conditions.
- biomimetic catalysis,
- metal-organic frameworks,
- polyoxometalates,
- synergistic catalysis
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