Citation: GONG Liaokuo, SONG Ying, SHEN Nannan, ZHANG Bo, WU Zhaofeng, HUANG Xiaoying. A Fluorescent Magnesium-Based Metal-Organic Framework with a Sensitive Sensing Property for Carbon Disulfide[J]. Chinese Journal of Applied Chemistry, ;2017, 34(9): 1059-1065. doi: 10.11944/j.issn.1000-0518.2017.09.170189 shu

A Fluorescent Magnesium-Based Metal-Organic Framework with a Sensitive Sensing Property for Carbon Disulfide

GONG Liaokuo ^a,b ,
SONG Ying ^a ,
SHEN Nannan ^a,b ,
ZHANG Bo ^a,b ,
WU Zhaofeng ^a,, ,
HUANG Xiaoying ^a,,

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: WU Zhaofeng, zfwu@fjirsm.ac.cn HUANG Xiaoying, xyhuang@fjirsm.ac.cn
Received Date: 1 June 2017
Revised Date: 19 June 2017
Accepted Date: 22 June 2017

Fund Project: the National Natural Science Foundation of China 21403233the 973 Program 2014CB845603Supported by the National Natural Science Foundation of China(No.21403233), the 973 Program(No.2014CB845603)

Figures(5)

Presented here are the solvothermal synthesis, structural characterization and fluorescent properties of a magnesium metal-organic framework(Mg-MOF), namely[Mg₄(1, 4-NDC)₄(DMA)₂(CH₃OH)₂(H₂O)₂]·DMA·CH₃OH(1, 1, 4-H₂NDC=1, 4-naphthalene dicarboxylic acid, DMA=N, N'-Dimethylacetamide). Single-crystal X-ray diffraction studies revealed that compound 1 crystallized in the monoclinic space group P2₁/c(No.14) with a=2.06090(12) nm, b=2.21014(13) nm, c=1.50385(10) nm, β=111.399(3)°, V=6.3776(7) nm³, Z=4, D_c=1.403 g/cm³, F(000)=2824, R=0.0596 and wR=0.1225(I>2σ(I)). The structure of compound 1 features a three-dimensional(3D) network constructed from the 1, 4-NDC ligands as bridging linkers and binuclear magnesium clusters as the secondary building units, with cages occupied by different solvent molecules of DMA and CH₃OH. Notably, fluorescence studies revealed that compound 1 demonstrated sensitive sensing towards carbon disulfide(CS₂); remarkably, the fluorescence intensity of compound 1 could be almost completely quenched at the low concentration of 0.4%(volume fraction) of CS₂. Thermal stability was investigated by thermogravimetric analysis which indicated that compound 1 could be stable up to 140℃.
- magnesium,
- metal-organic framework,
- fluorescence sensor,
- carbon disulfide
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