Citation: LI Na, CHANG Ze, BU Xianhe. A Tb³⁺ Coordination Polymer with Tetrazol Functional Sites:Construction and Fluorescent Sensing Property Toward Metal Ions[J]. Chinese Journal of Applied Chemistry, ;2017, 34(9): 1046-1051. doi: 10.11944/j.issn.1000-0518.2017.09.170188 shu

A Tb³⁺ Coordination Polymer with Tetrazol Functional Sites:Construction and Fluorescent Sensing Property Toward Metal Ions

LI Na ^a ,
CHANG Ze ^a,, ,
BU Xianhe ^a,b

a.
School of Materials Science and Engineering, National Institute for Advanced Materials, and Tianjin Key Laboratory of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin 300350, China
b.
College of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: CHANG Ze, changze@nankai.edu.cn
Received Date: 1 June 2017
Revised Date: 5 July 2017
Accepted Date: 5 July 2017

Fund Project: Supported by the National Natural Science Foundation of China(No.15JCZDJC38800, No.16JCQNJC02400)the National Natural Science Foundation of China 16JCQNJC02400the National Natural Science Foundation of China 15JCZDJC38800

Figures(4)

Lanthanide coordination polymers have been widely investigated in fluorescent sensing owing to their characters in component, structure, and properties. However, the functional targeted construction of lanthanide coordination polymers is still a challenge. Herein, we report the construction, characterization, and properties investigation of a new Tb³⁺ coordination polymer, namely[Tb(TZI)(DMF)₂(H₂O)]·(H₂O)(1)(H₃TZI=5-(1H-tetrazol-5-yl)isophthalic acid and DMF=N, N-dimethylmethanamide). Utilizing the distinct affinities between Tb³⁺ ion and carboxylate/tetrazole groups, the construction of coordination polymer is well achieved, while the tetrazole group has been introduced into the framework of coordination polymer as sensing sites. As a result, complex 1 reveals ions dependent emissions enhancement owing to the coordination between the ions and the tetrazole sites, which could be utilized for the sensing of Zn²⁺ and Na⁺ ions. These results could be instructive for the fluorescent sensing function targeted construction of lanthanide coordination polymers.
- coordination polymer,
- lanthanide metals,
- construction,
- fluorescent sensing
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南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com

A Tb³⁺ Coordination Polymer with Tetrazol Functional Sites:Construction and Fluorescent Sensing Property Toward Metal Ions