Citation: JIANG Zhiqiang, WANG Fei, ZHANG Jian. Rational Design of Zeolitic Tetrazolate Frameworks with Carboxylate Ligands for Rapid Accumulation of Iodine[J]. Chinese Journal of Applied Chemistry, ;2017, 34(9): 1072-1078. doi: 10.11944/j.issn.1000-0518.2017.09.170183 shu

Rational Design of Zeolitic Tetrazolate Frameworks with Carboxylate Ligands for Rapid Accumulation of Iodine

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou 350002, China
b.
Panzhihua Key Laboratory of Chemical Resource Engineering, Panzhihua University, Panzhihua, Sichuan 617000, China

Corresponding author: ZHANG Jian, zhj@fjirsm.ac.cn
Received Date: 27 May 2017
Revised Date: 26 June 2017
Accepted Date: 5 July 2017

Fund Project: the Science and Technology Planning Project in Panzhihua City 2016CY-G-4Supported by the National Natural Science Foundation of China(No.21573236), the Open Foundation of State Key Laboratory of Structural Chemistry(No.20150012), the Science and Technology Planning Project in Sichuan Province(No.2014GZ0030, No.2015RZ0029), the Science and Technology Planning Project in Panzhihua City(No.2014CY-G-24, No.2016CY-G-4)the National Natural Science Foundation of China 21573236the Open Foundation of State Key Laboratory of Structural Chemistry 20150012the Science and Technology Planning Project in Sichuan Province 2014GZ0030the Science and Technology Planning Project in Sichuan Province 2015RZ0029the Science and Technology Planning Project in Panzhihua City 2014CY-G-24

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Zeolitic metal-organic frameworks(MOFs) with high porosity, controlled pore size, regular pore shape, high thermal and chemical stability have been extensively studied and display potential applications in the field of rapid accumulation of iodine. Here, through simulating the structure of zeolite, two tetrahedral tetrazolate frameworks(TTF-8 and TTF-9) were successfully assembled via using thiophene-2, 5-dicarboxylate and 4, 4'-oxybisbenzoic acid as an auxiliary ligand, respectively. The results of single-crystal X-ray diffraction measurement show that TTF-8 crystallizes in a tetragonal space group of P4₂mc, while TTF-9 exhibits a monoclinic space group of P2₁/c. Remarkably, although TTF-8 and TTF-9 exhibit the same BCT topology, their frameworks and pore structures are entirely different. Two TTFs materials display outstanding performance on rapidly enriching iodine.
- zeolitic tetrazolate frameworks,
- assembly strategy,
- absorbing iodine
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