Citation: XIE Ruirui, WANG Qian, XUE Dongxu, ZHANG Zonghui, ZHANG Yufeng, BAI Junfeng. A Photoluminescent Anionic Metal-Organic Framework with Oxalamide Groups for Selective Methylene Blue Adsorption[J]. Chinese Journal of Applied Chemistry, ;2017, 34(9): 1066-1071. doi: 10.11944/j.issn.1000-0518.2017.09.170179 shu

A Photoluminescent Anionic Metal-Organic Framework with Oxalamide Groups for Selective Methylene Blue Adsorption

XIE Ruirui ^a ,
WANG Qian ^a ,
XUE Dongxu ^a,, ,
ZHANG Zonghui ^a ,
ZHANG Yufeng ^a ,
BAI Junfeng ^a,b,,

a.
Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an 710062, China
b.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Corresponding author: XUE Dongxu, xuedx@snnu.edu.cn BAI Junfeng, bjunfeng@nju.edu.cn
Received Date: 26 May 2017
Revised Date: 29 June 2017
Accepted Date: 3 July 2017

Fund Project: Supported by the Fundamental Research Funds for the Central Universities(No.GK201603044, No.GK201701004), the Shaanxi Provincial Natural Science Foundation of China(No.2016JM2016), the Cheung Kong Scholars Program and the 100 Talent Plan of Shaanxi Provincethe Fundamental Research Funds for the Central Universities GK201701004the Fundamental Research Funds for the Central Universities GK201603044the Shaanxi Provincial Natural Science Foundation of China 2016JM2016

Figures(5)

Adsorption of dyes has received wide attention due to its threat to human health and environment. In this work, a new oxalamide-functionalized anionic metal-organic framework {[(CH₃)₂NH₂]₂(CdL)}·x(Solvent)(1) has been successfully synthesized by virtue of a tetratopic ligand of 5, 5'-[oxalylbis(azanediyl)]diisophthalic acid (H₄L). Single crystal X-ray diffraction reveals that compound 1 exhibits a 2-fold interpenetrated 3D framework and (3, 3, 4)-connected topological network with a new point(Schläfli) symbol of {8³}₂{8⁶}. Interestingly, it displays not only selective adsorption capacity toward methylene blue(MB) over methyl orange(MO), but also the photoluminescence emission at visible region.
- anionic framework,
- new topology,
- adsorption of methylene blue
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