Citation: ZHENG Xiuying, KONG Xiangjian, LONG Lasheng, ZHENG Lansun. Synthesis, Structure, Magnetic Properties of Lanthanide Cluster-Based Metal-Organic Frameworks[J]. Chinese Journal of Applied Chemistry, ;2017, 34(9): 1086-1092. doi: 10.11944/j.issn.1000-0518.2017.09.170176 shu

Synthesis, Structure, Magnetic Properties of Lanthanide Cluster-Based Metal-Organic Frameworks

Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005, China

Corresponding author: KONG Xiangjian, xjkong@xmu.edu.cn LONG Lasheng, lslong@xmu.edu.cn
Received Date: 25 May 2017
Revised Date: 28 June 2017
Accepted Date: 28 June 2017

Fund Project: the National Natural Science Foundation of China 21371144the National Natural Science Foundation of China 21431005Supported by the National Natural Science Foundation of China(No.21422106, No.21371144, No.21431005)the National Natural Science Foundation of China 21422106

Figures(7)

Two lanthanide cluster-based metal-organic frameworks of {[Gd₇(OH)₈(HOCH₂COO)₈(H₂O)₃]·Cl₅·3H₂O}_n(Ln=Gd(1), Dy(2)) were obtained by solvothermal reaction. The magnetic studies indicate that compound 1 exhibits a large magnetocalotic effect(MCE) values of 44.4 J/(kg·K) at 2 K and △H=7 T and compound 2 displays obvious frequency dependence(H_dc=0) which suggests that compound 2 shows slow relaxation. In addition, the results of powder diffraction reveals that compounds 1 and 2 display very high chemical stability, which can be stable in acid/base solution of pH=1~14 and boiling water. These results indicate that the lanthanide cluster-based metal-organic frameworks have the potential application in the low-temperature refrigeration.
- lanthanide organic-metal frameworks,
- magnetocalotic effect,
- frequency dependence,
- chemical stability
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