Citation: DU Xiangsha, LI Haiyang, LIU Heng, LI Genheng, LI Linke, ZANG Shuangquan. Multi-Functional Viologen-Based Eu(Ⅲ) Complex with Photoswitchable Luminescence, Nonlinear Optical Properties and Photovoltaic Activity[J]. Chinese Journal of Applied Chemistry, ;2017, 34(9): 1024-1034. doi: 10.11944/j.issn.1000-0518.2017.09.170160 shu

Multi-Functional Viologen-Based Eu(Ⅲ) Complex with Photoswitchable Luminescence, Nonlinear Optical Properties and Photovoltaic Activity

College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: LI Linke, lilinke@zzu.edu.cn ZANG Shuangquan, zangsqzg@zzu.edu.cn
Received Date: 16 May 2017
Revised Date: 15 June 2016
Accepted Date: 30 June 2016

Fund Project: the National Natural Science Foundation of China 21371153the National Natural Science Foundation of China 20901070Supported by the National Natural Science Foundation of China(No.21371153, No.20901070), Program for Science & Key Scientific and Technological Project of Henan Province(No.132102210411), Key Scientific Research Project Plan in Colleges and Universities of Henan Province(No.16A150045)Program for Science & Key Scientific and Technological Project of Henan Province 132102210411Key Scientific Research Project Plan in Colleges and Universities of Henan Province 16A150045

Figures(8)

The solvothermal reaction of a viologen-functionalized aromatic dicarboxylate ligand 1-(3, 5-dicarboxybenzyl)-4, 4'-bipyridinium nitrate(H₂L⁺NO₃^-) with Eu(Ⅲ) leads to the formation of a new metal-organic complex {[Eu(μ₂-OH)(L)(HCO₂)]·H₂O}_n(1), in which the formate anions come from the in situ decomposition of solvent dimethylformamide(DMF). Single-crystal X-ray analysis revealed that complex 1 has chirality and diaplays a two-dimensional layer structure. Complex 1 manifests fast photoresponsive and reversibile photochromic properties. It gives an eye-detectable color change from pale-yellow to dark green upon exposure to light, and the coloring/fading processes can repeat several cycles. The structural analysis demonstrated that the electrons transfer from carboxylate donors to viologen acceptor as well as the π....π interaction offers reasonable electron-transfer pathways for the photochromic process. Interestingly, the synthesized solid-state chiral crystalline material not only exhibits tunable luminescence in response to light, but also shows photoswitching nonlinear optical(NLO) activity, and the second-harmonic generation(SHG) efficiency is approximately 3.8 times that of potassium dihydrogen phosphate(KDP) in the same particle size. Moreover, surface photovoltage spectroscopy(SPS) of complex 1 has been investigated and the result indicates it exhibits interesting photovoltaic activity.
- multi-functional,
- viologen-based,
- Eu(Ⅲ) complex,
- photoswitchable luminescence,
- nonlinear optical properties,
- photovoltaic activity
1. [1]
  Ungur L, Lin S Y, Tang J. Single-Molecule Toroics in Ising-type Lanthanide Molecular Clusters[J]. Chem Soc Rev, 2014,43(20):6894-6905. doi: 10.1039/C4CS00095A
2. [2]
  Bianchi A, Delgado-Pinar E, García-España E. Highlights of Metal Ion-based Photochemical Switches[J]. Coord Chem Rev, 2014,260:156-215. doi: 10.1016/j.ccr.2013.09.023
3. [3]
  Irie M, Fukaminato T, Matsuda K. Photochromism of Diarylethene Molecules and Crystals:Memories, Switches, and Actuators[J]. Chem Rev, 2014,114(24):12174-12277. doi: 10.1021/cr500249p
4. [4]
  Ratera I, Veciana J. Playing with Organic Radicals as Building Blocks for Functional Molecular Materials[J]. J Chem Soc Rev, 2012,41:303-349. doi: 10.1039/C1CS15165G
5. [5]
  Zhang T, Lin W. Metal-Organic Frameworks for Artificial Photosynthesis and Photocatalysis[J]. Chem Soc Rev, 2014,43:5982-5993. doi: 10.1039/C4CS00103F
6. [6]
  Guldi D M, Rahman G M A, Sgobba V. Multifunctional Molecular Carbon Materials from Fullerenes to Carbon Nanotubes[J]. Chem Soc Rev, 2006,35(5):471-487. doi: 10.1039/b511541h
7. [7]
  Train C, Gruselle M, Verdaguer M. The Fruitful Introduction of Chirality and Control of Absolute Configurations in Molecular Magnets[J]. Chem Soc Rev, 2011,40(6):3297-3312. doi: 10.1039/c1cs15012j
8. [8]
  Li P X, Wang M S, Cai L Z. Rare Electron-Transfer Photochromic and Thermochromic Difunctional Compounds[J]. J Mater Chem C, 2015,3(2):253-256. doi: 10.1039/C4TC01315H
9. [9]
  Liao J Z, Zhang H L, Wang S S. Multifunctional Radical-Doped Polyoxometalate-Based Host-Guest Material:Photochromism and Photocatalytic Activity[J]. Inorg Chem, 2015,54(9):4345-4350. doi: 10.1021/acs.inorgchem.5b00041
10. [10]
  Deng H, Doonan C J, Furukawa H. Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks[J]. Science, 2010,327(5697):846-850.
11. [11]
  Ryder M R, Tan J C. Nanoporous Metal Organic Framework Materials for Smart Applications[J]. J Mater Sci Technol, 2014,30(13):1598-1612. doi: 10.1179/1743284714Y.0000000550
12. [12]
  Wang M S, Xu G, Zhang Z J. Inorganic-Organic Hybrid Photochromic Materials[J]. Chem Commun, 2010,46(3):361-376. doi: 10.1039/B917890B
13. [13]
  Pardo R, Zayat M, Levy D. Photochromic Organic-Inorganic Hybrid Materials[J]. Chem Soc Rev, 2011,40(2):672-687. doi: 10.1039/c0cs00065e
14. [14]
  Yao Q X, Ju Z F, Jin X H. Novel Polythreaded Coordination Polymer:From an Armed-Polyrotaxane Sheet to a 3D Polypseudorotaxane Array, Photo-and Thermochromic Behaviors[J]. Inorg Chem, 2009,48(4):1266-1268. doi: 10.1021/ic8021672
15. [15]
  Yao Q X, Pan L, Ju X H. Bipyridinium Array-Type Porous Polymer Displaying Hydrogen Storage, Charge-Transfer-Type Guest Inclusion, and Tunable Magnetic Properties[J]. Chem-Eur J, 2009,15(44):11890-11897. doi: 10.1002/chem.v15:44
16. [16]
  Zhang C H, Sun L B, Zhang C Q. Novel Photo-and/or Thermochromic MOFs Derived from Bipyridinium Carboxylate Ligands[J]. Inorg Chem Front, 2016,3(6):814-820. doi: 10.1039/C6QI00013D
17. [17]
  Aulakh D, Nicoletta A P, Varghese J R. The Structural Diversity and Properties of Nine New Viologen Based Zwitterionic Metal-Organic Frameworks[J]. CrystEngComm, 2016,18(12):2189-2202. doi: 10.1039/C6CE00284F
18. [18]
  Deska M, Kozlowska J, Sliwa W. Rotaxanes and Pseudorotaxanes with Threads Containing Viologen Units[J]. ARKIVOC, 2013:66-100.
19. [19]
  Higuchi M, Nakamura K, Horike S. Design of Flexible Lewis Acidic Sites in Porous Coordination Polymers by Using the Viologen Moiety[J]. Angew Chem, 2012,124(33):8494-8497. doi: 10.1002/ange.v124.33
20. [20]
  Lin J B, Shimizu G K H. Pyridinium Linkers and Mixed Anions in Cationic Metal-Organic Frameworks[J]. Inorg Chem Front, 2014,1(4):302-305. doi: 10.1039/C3QI00065F
21. [21]
  Aulakh D, Varghese J R, Wriedt M. A New Design Strategy to Access Zwitterionic Metal Organic Frameworks from Anionic Viologen Derivates[J]. Inorg Chem, 2015,54(4):1756-1764. doi: 10.1021/ic5026813
22. [22]
  Sun J K, Zhang J. Functional Metal Bipyridinium Frameworks:Self-Assembly and Applications[J]. Dalton Trans, 2015,44:19041-19055. doi: 10.1039/C5DT03195H
23. [23]
  Sun J K, Wang P, Yao Q X. Solvent-and Anion-Controlled Photochromism of Viologen-Based Metal-Organic Hybrid Materials[J]. J Mater Chem, 2012,22(24):12212-12219. doi: 10.1039/c2jm30558e
24. [24]
  Sun J K, Cai L X, Chen Y J. Reversible Luminescence Switch in a Photochromic Metal Organic Framework[J]. Chem Commun, 2011,47(24):6870-6872. doi: 10.1039/c1cc11550b
25. [25]
  Chen H, Zheng G, Li M. Photo-and Thermo-Activated Electron Transfer System Based on a Luminescent Europium Organic Framework with Spectral Response from UV to Visible Range[J]. Chem Commun, 2014,50(88):13544-13546. doi: 10.1039/C4CC05975A
26. [26]
  Sun J K, Chen C, Cai L X. Mechanical Grinding of a Single-Crystalline Metal Mrganic Framework Triggered Emission with Tunable Violet-to-Orange Luminescence[J]. Chem Commun, 2014,50(100):15956-15959. doi: 10.1039/C4CC08316D
27. [27]
  Jin X H, Sun J K, Cai L X. 2D Flexible Metal Organic Frameworks with[J]. Chem Commun, 2011,47(9):2667-2669. doi: 10.1039/c0cc04084c
28. [28]
  Mitchell R H, Brkic Z, Sauro V A. A Photochromic, Electrochromic, Thermochromic Ru Complexed Benzannulene:An Organometallic Example of the Dimethyldihydropyrene-Metacyclophanediene Valence Isomerization[J]. J Am Chem Soc, 2003,125(25):7581-7585. doi: 10.1021/ja034807d
29. [29]
  Li M H, Keller P. Stimuli-Responsive Polymer Vesicles[J]. Soft Matter, 2009,5:927-937. doi: 10.1039/b815725a
30. [30]
  Jaffe A, Lin Y, Mao W L. Pressure-Induced Conductivity and Yellow-to-Black Piezochromism in a Layered Cu-Cl Hybrid Perovskite[J]. J Am Chem Soc, 2015,137(4):1673-1678. doi: 10.1021/ja512396m
31. [31]
  Wu J H, Liou G S. High-Performance Electrofluorochromic Devices Based on Electrochromism and Photoluminescence-Active Novel Poly(4-Cyanotriphenylamine)[J]. Adv Funct Mater, 2014,24(41):6422-6429. doi: 10.1002/adfm.v24.41
32. [32]
  Yao J, Hashimoto K, Fujishima A. Photochromism Induced in an Electrolytically Pretreated Mo03 Thin Film by Visible Light[J]. Nature, 1992,355:624-626. doi: 10.1038/355624a0
33. [33]
  Irie M. Diarylethenes for Memories and Switches[J]. Chem Rev, 2000,100(5):1685-1716. doi: 10.1021/cr980069d
34. [34]
  de Jong J J D, Lucas L N, Kellogg R M. Astronomers Attempt to Stay in the Big League[J]. Science, 2004,304(5669):378-380. doi: 10.1126/science.304.5669.378
35. [35]
  Li H Y, Xu H, Zang S Q. A Viologen-functionalized Chiral Eu-MOF as a Platform for Multifunctional Switchable Material[J]. Chem Commun, 2016,52(3):525-528. doi: 10.1039/C5CC08168H
36. [36]
  Li H Y, Wei Y L, Dong X Y. Novel Tb-MOF Embedded with Viologen Species for Multi-Photofunctionality:Photochromism, Photomodulated Fluorescence, and Luminescent pH Sensing[J]. Chem Mater, 2015,27(4):1327-1331. doi: 10.1021/cm504350q
37. [37]
  Lvaro Á, Ferrer M, Fornés V B. A Periodic Mesoporous Organosilica Containing Electron Acceptor Viologen Units[J]. Chem Commun, 2001,24:2546-2547.
38. [38]
  Park Y S, Um S Y, Yoon K B. Charge-Transfer Interaction of Methyl Viologen with Zeolite Framework and Dramatic Blue Shift of Methyl Viologen-Arene Charge-Transfer Band upon Increasing the Size of Alkali Metal Cation[J]. J Am Chem Soc, 1999,121(13):3193-3200. doi: 10.1021/ja980912p
39. [39]
  Berthet J J, Micheau C, Metelitsa A. Multistep Thermal Relaxation of Photoisomers in Polyphotochromic Molecules[J]. J Phys Chem A, 2004,108(50):10934-10940. doi: 10.1021/jp046864e
40. [40]
  Sheldrick G M. Acta Crystallogr, Sect. A:Fundam Crystallogr[M]. 1990, 46:457.
41. [41]
  Sheldrick G M. SHELXS-97, Program for Solution of Crystal Structures[M]. University of G ttingen, Germany, 1997.
42. [42]
  Sheldrick G M. SHELXL-97, Program for Refinement of Crystal Structures[M]. University of G ttingen, Germany, 1997.
43. [43]
  Tan Y, Fu Z Y, Zeng Y. Highly Stable Photochromic Crystalline Material Based on a Close-Packed Layered Metal-Viologen Coordination Polymer[J]. J Mater Chem, 2012,22(34):17452-17455. doi: 10.1039/c2jm34341j
44. [44]
  Toma O, Mercier N, Allain M. Photo-and Thermochromic and Adsorption Properties of Porous Coordination Polymers Based on Bipyridinium Carboxylate Ligands[J]. Inorg Chem, 2015,54(18):8923-8930. doi: 10.1021/acs.inorgchem.5b00975
45. [45]
  Matsunaga Y, Goto K, Kubono K. Photoinduced Color Change and Photomechanical Effect of Naphthalene Diimides Bearing Alkylamine Moieties in the Solid State[J]. Chem Eur J, 2014,20(24):7309-7316. doi: 10.1002/chem.201304849
46. [46]
  Xu G, Guo G C, Wang M S. Photochromism of a Methyl Viologen Bismuth(Ⅲ) Chloride:Structural Variation before and after UV Irradiation[J]. Angew Chem Int Ed, 2007,46(18):3249-3251. doi: 10.1002/(ISSN)1521-3773
47. [47]
  Xu G, Guo G C, Guo J S. Photochromic Inorganic-Organic Hybrid:A New Approach for Switchable Photoluminescence in the Solid State and Partial Photochromic Phenomenon[J]. Dalton Trans, 2010,39(37):8688-8692. doi: 10.1039/c0dt00471e
48. [48]
  Lin R G, Xu G, Wang M S. Improved Photochromic Properties on Viologen-Based Inorganic-Organic Hybrids by Using π-Conjugated Substituents as Electron Donors and Stabilizers[J]. Inorg Chem, 2013,52(3):1199-1205. doi: 10.1021/ic301181b
49. [49]
  Sun J K, Ji M, Chen C. A Charge-Polarized Porous Metal-Organic Framework for Gas Chromatographic Separation of Alcohols from Water[J]. Chem Commun, 2013,49(16):1624-1626. doi: 10.1039/c3cc38260e
50. [50]
  Hutchison G R, Ratner M A, Marks T J. Intermolecular Charge Transfer Between Heterocyclic Oligomers. Effects of Heteroatom and Molecular Packing on Hopping Transport in Organic Semiconductors[J]. J Am Chem Soc, 2005,127(48):16866-16881. doi: 10.1021/ja0533996
51. [51]
  Jhang P C, Chuang N T, Wang S L. Layered Zinc Phosphates with Photoluminescence and Photochromism:Chemistry in Deep Eutectic Solvents[J]. Angew Chem Int Ed, 2010,49(25):4200-4204. doi: 10.1002/anie.v49:25
52. [52]
  Lin R G, Xu G, Lu G. Photochromic Hybrid Containing In Situ-Generated Benzyl Viologen and Novel Trinuclear[Bi₃Cl₁₄]^5-:Improved Photoresponsive Behavior by the π…π[JG)] Interactions and Size Effect of Inorganic Oligomer[J]. Inorg Chem, 2014,53(11):5538-5545. doi: 10.1021/ic5002144
53. [53]
  Yoshikawa H, Nishikiori S I, Watanabe T. Polycyano-Polycadmate Host Clathrates Including a Methylviologen Dication. Syntheses, Crystal Structures and Photo-Induced Reduction of Methylviologen Dication[J]. J Chem Soc Dalton Trans, 2002,43(9):1907-1917.
54. [54]
  Jin X H, Sun J K, Xu X M. Conformational and Photosensitive Adjustment of the 4, 4'-Bipyridinium in Mn(Ⅱ) Coordination Complexes[J]. Chem Commun, 2010,46(26):4695-4697. doi: 10.1039/c0cc00135j
55. [55]
  Sava D F, Rohwer L E S, Rodriguez M A. Intrinsic Broad-Band White-Light Emission by a Tuned, Corrugated Metal-Organic Framework[J]. J Am Chem Soc, 2012,134(9):3983-3986. doi: 10.1021/ja211230p
56. [56]
  Xu H, Cao C S, Zhao B. A Water-Stable Lanthanide-Organic Framework as a Recyclable Luminescent Probe for Detecting Pollutant Phosphorus Anions[J]. Chem Commun, 2015,51:10280-10283. doi: 10.1039/C5CC02596F
57. [57]
  Xu H, Cao C S, Kang X M. Lanthanide-Based Metal Organic Frameworks as Luminescent Probes[J]. Dalton Trans, 2016,45(45):18003-18017. doi: 10.1039/C6DT02213H
58. [58]
  Xu H, Zhai B, Cao C S. A Bifunctional Europium-Organic Framework with Chemical Fixation of CO₂ and Luminescent Detection of Al³⁺[J]. Inorg Chem, 2016,55(19):9671-9676. doi: 10.1021/acs.inorgchem.6b01407
59. [59]
  Li H N, Li H Y, Li L K. Syntheses, Structures, and Photoluminescent Properties of Lanthanide Coordination Polymers Based on a Zwitterionic Aromatic Polycarboxylate Ligand[J]. Cryst Growth Des, 2015,15(9):4331-4340. doi: 10.1021/acs.cgd.5b00625
60. [60]
  Ma M L, Ji C, Zang S Q. Syntheses, Structures, Tunable Emission and White Light Emitting Eu³⁺ and Tb³⁺ Doped Lanthanide Metal Organic Framework Materials[J]. Dalton Trans, 2013,42(29):10579-10586. doi: 10.1039/c3dt50315a
61. [61]
  Jain K, Pratt G W. Optical Transistor[J]. Appl Phys Lett, 1976,28:719-721. doi: 10.1063/1.88627
62. [62]
  Zyss J, Chemla D S. Nonlinear Optical Properties of Organic Molecules and Crystals[M]. New York:Academic Press, 1989, 1:23-191.
63. [63]
  Keszler D A. Synthesis, Crystal Chemistry, and Optical Properties of Metal Borates[J]. Curr Opin Solid State Mater Sci, 1999,4(2):155-162. doi: 10.1016/S1359-0286(99)00011-X
64. [64]
  Nye J F. Physical Properties of Crystals:Their Representation by Tensors and Matrices[M]. Clarendon, Oxford, 1985.
65. [65]
  Bella S D. Second-Order Nonlinear Optical Properties of Transition Metal Complexes[J]. Chem Soc Rev, 2001,30(6):355-366. doi: 10.1039/b100820j
66. [66]
  Li P X, Wang M S, Zhang M J. Electron-Transfer Photochromism to Switch Bulk Second-Order Nonlinear Optical Properties with High Contrast[J]. Angew Chem Int Ed, 2014,53(43):11529-11531. doi: 10.1002/anie.201406554
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