Citation: WANG Zheng, YIN Shaoyun, PAN Mei, LIU Yu, SUN Sisi, WANG Haiping, FAN Ya'nan, SU Chengyong. Assembly and Luminescence of Mononuclear Ln to Heteronuclear Ln-M Supramolecular Complexes[J]. Chinese Journal of Applied Chemistry, ;2017, 34(9): 1017-1023. doi: 10.11944/j.issn.1000-0518.2017.09.170144 shu

Assembly and Luminescence of Mononuclear Ln to Heteronuclear Ln-M Supramolecular Complexes

Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, China

Corresponding author: PAN Mei, panm@mail.sysu.edu.cn
Received Date: 8 May 2017
Revised Date: 1 June 2017
Accepted Date: 2 June 2017

Fund Project: the Science and Technology Planning Project of Guangzhou 201504010031the National Natural Science Foundation of China 21373276the Science and Technology Planning Project of Guangzhou 201510010246Supported by the National Natural Science Foundation of China(No.21373276), the Science and Technology Planning Project of Guangzhou (No.201510010246, No.201504010031)

Figures(4)

Via stepwise assembly method, discrete mononuclear Ln(Ln=Tb/Sm/Yb) complexes were synthesized from 3-or 4-pyridyl modified tripodal ligands, which were then assembled into three dimensional Ln-M(M=Ag or Cd) metal-organic frameworks(MOFs) with different topologies through the linkage of pyridyl ends. The heteronuclear MOFs sustain a characteristic emission of Ln³⁺ coordination centers, but the energy levels of the ligands are lowered in the three-dimensional packing structures, which affects the energy transfer efficiency to lanthanide centers. As a result, a stronger near-infrared luminescence is obtained in 2-Yb-Ag compared with its mononuclear counterpart, and the decay lifetime increases from 4.3 μs to 6.7 μs. While 4-Tb-Cd simultaneously emits metal-centered and ligand-based emissions, in which the decay lifetime for Tb-centered emission shortens from 2.91 ms to 0.62 ms compared with the corresponding mononuclear complex.
- lanthanide emission,
- metal-organic framework,
- heteronuclear complex
1. [1]
  Bünzli J C G. On the Design of Highly Luminescent Lanthanide Complexes[J]. Coord Chem Rev, 2015,293/294:19-47. doi: 10.1016/j.ccr.2014.10.013
2. [2]
  Barry D E, Caffrey D F, Gunnlaugsson T. Lanthanide-Directed Synthesis of Luminescent Self-Assembly Supramolecular Structures and Mechanically Bonded Systems from Acyclic Coordinating Organic Ligands[J]. Chem Soc Rev, 2016,45(11):3244-74. doi: 10.1039/C6CS00116E
3. [3]
  Xu L J, Xu G T, Chen Z N. Recent Advances in Lanthanide Luminescence with Metal-Organic Chromophores as Sensitizers[J]. Coord Chem Rev, 2014,273/274:47-62. doi: 10.1016/j.ccr.2013.11.021
4. [4]
  Liu Y, Pan M, Yang Q Y. Dual-Emission from a Single-Phase Eu-Ag Metal-Organic Framework:An Alternative Way to Get White-Light Phosphor[J]. Chem Mater, 2012,24(10):1954-1960. doi: 10.1021/cm3008254
5. [5]
  Pan M, Du B B, Zhu Y X. Highly Efficient Visible-to-NIR Luminescence of LnⅢ) Complexes with Zwitterionic Ligands Bearing Charge Transfer Character:Beyond Triplet Sensitization[J]. Chem Eur J, 2016,22(7):2440-2451. doi: 10.1002/chem.201504344
6. [6]
  Du B B, Zhu Y X, Pan M. Direct White-Light and Dual-channel Barcode Module from Pr(Ⅲ)-MOF Crystals[J]. Chem Commun, 2015,51(63):12533-12536. doi: 10.1039/C5CC04468E
7. [7]
  Pan M, Yan C, Chen L. Photoluminescence and White-Light Emitting in Two Series of Heteronuclear Pb(Ⅱ)-Ln(Ⅲ) Complexes[J]. New J Chem, 2015,39(5):3770-3776. doi: 10.1039/C5NJ00168D
8. [8]
  Yang Q Y, Wu K, Jiang J J. Pure White-Light and Yellow-to-Blue Emission Tuning in Single Crystals of Dy(Ⅲ) Metal-Organic Frameworks[J]. Chem Commun, 2014,50(57):7702-7704. doi: 10.1039/C4CC01763C
9. [9]
  He J, Huang J, He Y H. A Boiling-Water-Stable, Tunable White-Emitting Metal-Organic Framework from Soft-Imprint Synthesis[J]. Chem Eur J, 2016,22(5):1597-1601. doi: 10.1002/chem.201504941
10. [10]
  Zhou J M, Li H H, Zhang H. A Bimetallic Lanthanide Metal-Organic Material as a Self-Calibrating Color-Gradient Luminescent Sensor[J]. Adv Mater, 2015,27(44):7072-7077. doi: 10.1002/adma.201502760
11. [11]
  Wang L, Xie Z G, Dang S. Self-Assembly of Tunable Heterometallic Ln-Ru Coordination Polymers with Near-Infrared Luminescence and Magnetocaloric Effect[J]. Chem Eur J, 2017,23(12):2852-2857. doi: 10.1002/chem.v23.12
12. [12]
  Chen L, Zhang H, Pan M. An Efficient Visible and NIR Emitting Sm(Ⅲ) Metal-Organic Framework(Sm-MOF) Sensitized by Excited-State Intramolecular Proton Transfer(ESIPT) Ligand[J]. Chem Asian J, 2016,11(12):1765-1769. doi: 10.1002/asia.v11.12
13. [13]
  Zhang L Y, Li K, Pan M. Observation of Cascade f→d→f Energy Transfer in Sensitizing Near-Infrared(NIR) Lanthanide Complexes Containing Ru(Ⅱ) Polypyridine Metalloligand[J]. New J Chem, 2016,40(6):5379-5386. doi: 10.1039/C6NJ00089D
14. [14]
  Zhang L Y, Hou Y J, Pan M. Near-Infrared(NIR) Emitting Nd/Yb(Ⅲ) Complexes Sensitized by MLCT States of Ru(Ⅱ)/Ir(Ⅲ) Metalloligands in Visible Light Region[J]. Dalton Trans, 2015,44(34):15212-15219. doi: 10.1039/C5DT00545K
15. [15]
  Ning Y Y, Ke X S, Hu J Y. Bioinspired Orientation of β-Substituents on Porphyrin Antenna Ligands Switches Ytterbium(Ⅲ) NIR Emission with Thermosensitivity[J]. Inorg Chem, 2017,56(4):1897-1905. doi: 10.1021/acs.inorgchem.6b02481
16. [16]
  Pan M, Zheng X L, Liu Y. Structural and Photoluminescent Studies of Lanthanide Complexes with Tripodal TriRNTB(N-Substituted Tris(Benzimidazol-2-ylmethyl)Amine):Ligand Substituent, Anionic and Secondary Ligand Effects[J]. Dalton Trans, 2009,12(12):2157-2169.
1. [1]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
2. [2]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
3. [3]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
4. [4]
  Shiyi WANG , Chaolong CHEN , Xiangjian KONG , Lansun ZHENG , Lasheng LONG . Polynuclear lanthanide compound [Ce₄^ⅢCe₆^Ⅳ(μ₃-O)₄(μ₄-O)₄(acac)₁₄(CH₃O)₆]·2CH₃OH for the hydroboration of amides to amine. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 88-96. doi: 10.11862/CJIC.20240342
5. [5]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
6. [6]
  Xiaofang DONG , Yue YANG , Shen WANG , Xiaofang HAO , Yuxia WANG , Peng CHENG . Research progress of conductive metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 14-34. doi: 10.11862/CJIC.20240388
7. [7]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
8. [8]
  Qianlang Wang , Jijun Sun , Qian Chen , Quanqin Zhao , Baojuan Xi . The Appeal of Organophosphorus Compounds: Clearing Their Name. University Chemistry, 2025, 40(4): 299-306. doi: 10.12461/PKU.DXHX202405205
9. [9]
  Cheng Zheng , Shiying Zheng , Yanping Zhang , Shoutian Zheng , Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, 2024, 39(7): 322-329. doi: 10.3866/PKU.DXHX202310131
10. [10]
  Hong CAI , Jiewen WU , Jingyun LI , Lixian CHEN , Siqi XIAO , Dan LI . Synthesis of a zinc-cobalt bimetallic adenine metal-organic framework for the recognition of sulfur-containing amino acids. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 114-122. doi: 10.11862/CJIC.20240382
11. [11]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
12. [12]
  Shiyang He , Dandan Chu , Zhixin Pang , Yuhang Du , Jiayi Wang , Yuhong Chen , Yumeng Su , Jianhua Qin , Xiangrong Pan , Zhan Zhou , Jingguo Li , Lufang Ma , Chaoliang Tan . 铂单原子功能化的二维Al-TCPP金属-有机框架纳米片用于增强光动力抗菌治疗. Acta Physico-Chimica Sinica, 2025, 41(5): 100046-. doi: 10.1016/j.actphy.2025.100046
13. [13]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
14. [14]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
15. [15]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
16. [16]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
17. [17]
  .
  CCS Chemistry 综述推荐│绿色氧化新思路：光/电催化助力有机物高效升级
  . CCS Chemistry, 2025, 7(10.31635/ccschem.024.202405369): -.
18. [18]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
19. [19]
  Aiai WANG , Lu ZHAO , Yunfeng BAI , Feng FENG . Research progress of bimetallic organic framework in tumor diagnosis and treatment. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1825-1839. doi: 10.11862/CJIC.20240225
20. [20]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(1044)
HTML views(165)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142