Citation: MENG Yinxia, LI Zhanguo, FENG Yuxiang, ZHANG Jidong. Variation of the Methylamine Lead Iodine Precursor Thin Films During Aging and Its Influence on the Subsequent Perovskite Thin Films[J]. Chinese Journal of Applied Chemistry, ;2017, 34(7): 818-823. doi: 10.11944/j.issn.1000-0518.2017.07.160417 shu

Variation of the Methylamine Lead Iodine Precursor Thin Films During Aging and Its Influence on the Subsequent Perovskite Thin Films

MENG Yinxia ^a,b ,
LI Zhanguo ^a,*,, ,
FENG Yuxiang ^b ,
ZHANG Jidong ^b,*,,

a.
State Key Laboratory on High Power Semicondutor Lasers, Changchun University of Science and Technology, Changchun 130022, China
b.
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Corresponding author: LI Zhanguo, lzhg000@126.com ZHANG Jidong, jdzhang@ciac.ac.cn
Received Date: 17 October 2016
Revised Date: 21 November 2016
Accepted Date: 29 December 2016

Fund Project: the National Natural Science Foundation of China 61430037Project of Science and Technology Department of Jilin Province 20140520139JHthe National Natural Science Foundation of China 11474036Foundation of Education Department of Jilin Province 2015174

Figures(5)

Variation of the methylamine lead iodine(MAPbI₃) precursor thin films during aging at room temperature in the air was studied. With the aging time increasing, more MAPbI₃ perovskite is generated and after about 220 min it reaches a stable value while some precursors are still left. The influence of such variation on the subsequent MAPbI₃ perovskite thin films was also studied. The X-ray diffraction intensity and UV-Vis absorption of methylamine lead iodine precursor films after aging were lower than those of the as prepared films. The comparison of atomic force microscopy(AFM) surface morphology after thermal annealing shows that the crystalline grain size of thin film made from aged precursor thin film is much smaller than that made from the as prepared precursor film, the crystalline grain size of aged film is about 0.2 μm, and that of the as prepared one is 1.1 m. These phenomena are due to the more MAPbI₃ are generated during aging, which acts as more crystal nuclei that lead to smaller crystal grains and lower degree of crystallinity. This work provides a new idea and direction to explore the formation mechanism of methylamine lead iodide perovskite, which is the basic research of methylamine lead iodide perovskite thin film properties. The work has a certain guiding role in the practical production and industrial application in photovoltaic field.
- methylamine lead iodine precursor thin films,
- aging process,
- variation,
- thermal annealing
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