Citation: WANG Jiaming, GULMIRA·Turdi, YAN Yin, PAYZULLA·Ibirayimhaji, ABLIZ Yimit. Gas-sensing Properties to Ethylenediamine Based on Tetraphenylporphyrin Iron Sensitive Film Optical Waveguide Sensor[J]. Chinese Journal of Applied Chemistry, ;2017, 34(7): 847-854. doi: 10.11944/j.issn.1000-0518.2017.07.160414 shu

Gas-sensing Properties to Ethylenediamine Based on Tetraphenylporphyrin Iron Sensitive Film Optical Waveguide Sensor

a.
College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China
b.
College of Chemistry and Environmental Science, Kashgar University, Kashgar, Xinjiang 844006, China

Corresponding author: ABLIZ Yimit, ablizyimit@xju.edu.cn
Received Date: 14 October 2016
Revised Date: 28 December 2016
Accepted Date: 19 January 2017

Fund Project: the National Natural Science Foundation of China 21265020

Figures(9)

To detect ethylenediamine gas produced by the degradation of flavor during food deterioration process, tetraphenylporphyrin iron was synthesized via Alder method and its thin film/K⁺ exchanged glass waveguide sensor were prepared by spin coating. This sensor exhibits selective and high sensitive response to ethylenediamine. In the volume ratio range of 1×10^-10~1×10^-4(V/V₀), there is a good linear relationship between the volume ratio and output light intensity(R=0.9940). The response time and recovery time are 3 s and 11 s, respectively. The signal to noise ratio(S/N) is 4.8, RSD=0.5%(V/V₀=1×10^-7). Good linear relationship between the volume ratio and output light intensity(R=0.9985) in parallel experiments also proves the accuracy of this sensor toward ethylenediamine gas detection. This sensor has potential application in the field of food quality examination.
- tetraphenylporphyrin iron,
- optical waveguide sensor,
- ethylenediamine,
- gas sensing
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