Advanced Search

Citation: YANG Yu, WANG Zhipeng, WANG Honghua, ZHOU Guangyuan, ZHU Xiaofei. Preparation and Characterization of Poly(aryl ether sulfone) Copolymers Containing Imidazolyl Group[J]. Chinese Journal of Applied Chemistry, ;2017, 34(6): 623-630. doi: 10.11944/j.issn.1000-0518.2017.06.160381 shu

Preparation and Characterization of Poly(aryl ether sulfone) Copolymers Containing Imidazolyl Group

  • a.

    Institute of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, China

  • b.

    Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

  • c.

    Changzhou Institute of Energy Storage Meterials & Devices, Changzhou, Jiangsu 213002, China

  • Corresponding author: ZHOU Guangyuan, gyzhou@ciac.ac.cn ZHU Xiaofei, zhuxiaofei@ccut.edu.cn
  • Received Date: 21 September 2016
    Revised Date: 3 November 2016
    Accepted Date: 6 December 2016

    Fund Project: National High Technology Research and Development Projects 2015AA033901

Figures(6)

  • A series of different content of benzimidazolone and 5, 6-dimethyl-2-benzimidazolone poly(aryl ether sulfone) copolymers with side groups were synthesized by copolymerization on the basis of poly(aryl ether sulfone) with cardo group(PES-C). The structures and properties of the copolymers were characterized by nuclear magnetic resonance spectroscopy(NMR), Fourier transform infrared spectrometer(FTIR), thermal gravimetric analyzer(TGA) and so on. The resulsts show that poly(aryl ether sulfone) copolymers are amorphous. The copolymers exhibit good heat resistance, and present a single glass transition temperature(Tg>271℃), when the mole fraction of benzimidazolone and 5, 6-dimethyl-2-benzimidazolone increases, the copolymer glass transition temperature rises, ranging from 270℃ to 318℃ and 314℃, respectively. At the same time, the copolymers have good thermal stability. These copolymers have good solubility in N, N-dimethyl formamide(DMF), N, N-dimethylacetamide(DMAc), dimethyl sulfoxide(DMSO), N-methyl pyrrolidone(NMP) which are the commonly polar aprotic solvents, and trichloromethane(CHCl3). Based on good solution processability and film-forming properties, the toughness thin film can be prepared by solution preparation.
  • 加载中
    1. [1]

      HE Wei, LIAO Gongxiong, JIN Qifeng. Kinetics of Thermal Degradation of Special Engineering Thermoplastics PPESK and PPES and Life Estimation[J]. J Chem Ind Eng, 2006,57(4):982-986.  

    2. [2]

      WANG Lei, LI Jinhu, ZHU Guangming. Synthesis and Characterization of High Temperature Resistant Poly(aryl ether sulfone)[J]. China Plast Ind, 2007,35(8):11-13.  

    3. [3]

      WANG Zhipeng, WANG Feifei, WANG Honghua. Preparation and Characterization of Poly(aryl ether ketone) Containing Bisphenol A and Benzimidazolone[J]. Chinese J Appl Chem, 2015,32(5):505-509.  

    4. [4]

      TAN Zhengde, ZHAO Xiaozhu. Preparation and Application of PES Membrane[J]. China J Hunan Inst, 2003,13(1):84-87.  

    5. [5]

      TANG Anbin, LIU Xiaobo, CAI Xingxian. Research Progress of Poly(aryl ether sulfone) Modification[J]. China New Chem Mater, 1998(1):13-22.  

    6. [6]

      WANG Qinhong. Study on the Relationship of Molecular Chain Structure and Properties of Poly(aryl ether sulfone)[M]. Changchun:Jilin University, 2015(in Chinese).

    7. [7]

      CHEN Lie, SONG Caisheng, WEN Hongli. Synthesis and Characterization of Poly(aryl ether sulfone ether ketone ketone) Random Copolymers Prepared by 2, 2-6, 6-Tetramethyl-4, 4-Diphenoxydiphenlysulfone, Diphenether and Terephthaloyl Chloride[J]. Chinese J Process Eng, 2004,4(5):416-419.  

    8. [8]

      TONG Yongfen, SONG Caisheng, CHEN Lie. Synthesis and Characterization of Poly(aryl ether ketone) Copolymers with Methyl-Pendent Group[J]. Polym Mater Sci Eng, 2005,21(4):71-76.  

    9. [9]

      Wang S J, Meng Y Z, Hlil A R. Synthesis and Characterization of Phthalazinone Containing Poly(arylene ether)s, Poly(arylenethioether)s, and Poly(arylenesulfone)s via a Novel N-C Coupling Reaction[J]. Macromolecules, 2004,37(1):60-65. doi: 10.1021/ma030246z

    10. [10]

      LIU Xiaoling, LIN Shuying, LUO Qiuyan. Synthesis and Characterization of Novel Methyl Substituted Poly(aryl ether ketone ether sulfone ether ketone) Random Copolymers[J]. J Jiangxi Normal Univ, 2005,29(3):190-192.  

    11. [11]

      PENG Weiya, WANG Chenyi, WANG Ying. Synthesis and Properties of High Temperature Resistance Copoly(aryl ether sulfone)s Containing a 4-Fluorophenyl Group[J]. China New Chem Mater, 2009,37(2):23-25.  

    12. [12]

      YIN Haoyue, HUANG Shengjie, ZHANG Zhen. In Situ Synthesis of Polystyrene/SiO2 Hybrid Materials[J]. China Synth Resin Plast, 2014,31(5):14-17.  

    13. [13]

      Mir A A, Matsumura S, Hlil A R. Synthesis and Properties of Polymers Containing 2H-Benzimidazol-2-one Moieties:Polymerization via N-C Coupling Reactions[J]. ACS Macro Lett, 2012,1(1):194-197. doi: 10.1021/mz200138v

    14. [14]

      LIU Fuhui, WANG Zhipeng, WANG Honghua. Preparation and Properties of Amorphous Poly(aryl ether nitrile ketone) Copolymer for High Performance Coatings[J]. China J Funct Polym, 2014,27(1):99-103.  

    15. [15]

      WANG Zhipeng, WANG Feifei, WANG Honghua. Synthesis of Amorphous Polyaryletherketone Containing Phthalein and Fluorene as Side Groups[J]. Chem J Chinese Univ, 2014,35(11):2487-2493.  

  • 加载中
    1. [1]

      Hongling Yuan ,  Jialin Xie ,  Jiawei Wang ,  Jixiang Zhao ,  Jiayan Liu ,  Qing Feng ,  Wei Qi ,  Min Liu . Cyclic Olefin Copolymer (COC): The Agile Vanguard in the Realm of Materials. University Chemistry, 2024, 39(7): 294-298. doi: 10.12461/PKU.DXHX202311041

    2. [2]

      Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306

    3. [3]

      . 

      南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

      . CCS Chemistry, 2025, 7(0): -.

    4. [4]

      Hong Zheng ,  Xin Peng ,  Chunwang Yi . The Tale of Caprolactam Cyclic Oligomers: The Ever-changing Life of “Princess Cyclo”. University Chemistry, 2024, 39(9): 40-47. doi: 10.12461/PKU.DXHX202403058

    5. [5]

      Zhuoming Liang ,  Ming Chen ,  Zhiwen Zheng ,  Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By 1H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029

    6. [6]

      Hailian Tang ,  Siyuan Chen ,  Qiaoyun Liu ,  Guoyi Bai ,  Botao Qiao ,  Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004

    7. [7]

      Jiayu Gu ,  Siqi Wang ,  Jun Ling . Kinetics of Living Copolymerization: A Brief Discussion. University Chemistry, 2025, 40(4): 100-107. doi: 10.12461/PKU.DXHX202406012

    8. [8]

      Lihui Jiang ,  Wanrong Dong ,  Hua Yang ,  Yongqing Xia ,  Hongjian Peng ,  Jun Yuan ,  Xiaoqian Hu ,  Zihan Zeng ,  Yingping Zou ,  Yiming Luo . Study on Extraction of p-Hydroxyacetophenone. University Chemistry, 2024, 39(11): 259-268. doi: 10.12461/PKU.DXHX202402056

    9. [9]

      Linbao Zhang ,  Weisi Guo ,  Shuwen Wang ,  Ran Song ,  Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009

    10. [10]

      Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs3Bi2X9 (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282

    11. [11]

      Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm3+-doped Ba0.85Ca0.15Ti0.90Zr0.10O3 lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388

    12. [12]

      Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407

    13. [13]

      Yue Zhao ,  Yanfei Li ,  Tao Xiong . Copper Hydride-Catalyzed Nucleophilic Additions of Unsaturated Hydrocarbons to Aldehydes and Ketones. University Chemistry, 2024, 39(4): 280-285. doi: 10.3866/PKU.DXHX202309001

    14. [14]

      Liangzhen Hu ,  Li Ni ,  Ziyi Liu ,  Xiaohui Zhang ,  Bo Qin ,  Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001

    15. [15]

      Guojie Xu ,  Fang Yu ,  Yunxia Wang ,  Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060

    16. [16]

      Min LIU , Huapeng RUAN , Zhongtao FENG , Xue DONG , Haiyan CUI , Xinping WANG . Neutral boron-containing radical dimers. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 123-130. doi: 10.11862/CJIC.20240362

    17. [17]

      Guang Huang ,  Lei Li ,  Dingyi Zhang ,  Xingze Wang ,  Yugai Huang ,  Wenhui Liang ,  Zhifen Guo ,  Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051

    18. [18]

      Wenjie SHI , Fan LU , Mengwei CHEN , Jin WANG , Yingfeng HAN . Synthesis and host-guest properties of imidazolium-functionalized zirconium metal-organic cage. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 105-113. doi: 10.11862/CJIC.20240360

    19. [19]

      Rui Gao ,  Ying Zhou ,  Yifan Hu ,  Siyuan Chen ,  Shouhong Xu ,  Qianfu Luo ,  Wenqing Zhang . Design, Synthesis and Performance Experiment of Novel Photoswitchable Hybrid Tetraarylethenes. University Chemistry, 2024, 39(5): 125-133. doi: 10.3866/PKU.DXHX202310050

    20. [20]

      Yongqing Kuang ,  Jie Liu ,  Jianjun Feng ,  Wen Yang ,  Shuanglian Cai ,  Ling Shi . Experimental Design for the Two-Step Synthesis of Paracetamol from 4-Hydroxyacetophenone. University Chemistry, 2024, 39(8): 331-337. doi: 10.12461/PKU.DXHX202403012

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(373)
  • HTML views(62)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return