Citation: CHEN Ziting, LIANG Ying. Preparation and Application of Pd Nanomaterials Grown in situ on Non-Through-Hole Porous Alumina[J]. Chinese Journal of Applied Chemistry, ;2017, 34(6): 705-711. doi: 10.11944/j.issn.1000-0518.2017.06.160329 shu

Preparation and Application of Pd Nanomaterials Grown in situ on Non-Through-Hole Porous Alumina

CHEN Ziting ,
LIANG Ying ^*,,

School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Guangzhou 510006, China

Corresponding author: LIANG Ying, lyingair@126.com
Received Date: 18 August 2016
Revised Date: 16 November 2016
Accepted Date: 16 January 2017

Fund Project: the National Natural Science Foundation of China 21201043

Figures(5)

Using non-through-hole anodic aluminum oxide(AAO) as templates, with Al substrate as support body, Pd nanomaterials were prepared in situ in the channels of AAO with Al substrate as reducing agent. The removal of barrier layer and acid corrosion post-treatment of synthesized Pd/AAO were studied. The Pd morphologies under different situations were observed by scanning electronic microscopy. A plausible mechanism of Pd formation was proposed. The catalytic activity for Suzuki reaction of 4-bromobenzene carboxylic acid and phenylboronic acid was investigated with Pd/AAO as heterogeneous catalysts. It is found that Pd/AAO catalysts exhibit excellent catalytic activity, and the yield is up to 99.8% with 0.06% molar fraction of Pd. The catalysts with sheet structure are easily separated for recovery by just taking out of the solution and can be reused in the next time. This research gives a practical method for the design of heterogeneous catalysts in organic reactions.
- porous alumina,
- barrier layer,
- Pd,
- Suzuki reaction
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