Citation: LIN Hongyan, SUN Junjun, WANG Qinglin, ZENG Ling, LIU Guocheng, LIN Jiafeng. A Three-Dimensional Zinc Compound Based on One-Dimensional [H₂Mo₄O₁₄]_n^2n- Chain and Bis(pyridyl)-Bis(amide) Ligand: Synthesis, Structure and Property[J]. Chinese Journal of Applied Chemistry, ;2017, 34(6): 693-699. doi: 10.11944/j.issn.1000-0518.2017.06.160307 shu

A Three-Dimensional Zinc Compound Based on One-Dimensional [H₂Mo₄O₁₄]_n^2n- Chain and Bis(pyridyl)-Bis(amide) Ligand: Synthesis, Structure and Property

College of Chemistry and Chemical Engineering, Bohai University, Jinzhou, Liaoning 121013, China

Corresponding author: LIN Hongyan, linhongyan_2015@126.com
Received Date: 8 August 2016
Revised Date: 28 September 2016
Accepted Date: 9 October 2016

Fund Project: the National Natural Science Foundation of China 21501013the National Natural Science Foundation of China 21401010

Figures(5)

A three-dimensional(3D)zinc compound [Zn(3-bpye)(H₂Mo₄O₁₄)(H₂O)₂](3-bpye=N, N'-bis(3-pyridinecarboxamide)-1, 2-ethane) based on one-dimensional(1D) [H₂Mo₄O₁₄]_n^2n- chain was hydrothermally prepared by bis(pyridyl)-bis(amide) ligand, ammonium molybdate and zinc chloride. Structural analysis by element analysis, indrared(IR) spectroscopy, thermogravity(TG) and X-ray single-crystal diffraction(XRD) reveal that the title compound is triclinic system with P-1 space group. Its cell parameters are a=0.61310(3) nm, b=1.04750(6) nm, c=1.06540(6) nm, α=78.5540(10)°, β=77.5350(10)°, γ=89.9050(10)°, V=0.65420(6) nm³, M_r=981.47, D_c=2.491 g/cm³, Z=1, F(000)=468, R₁=0.0290, ωR₂=0.1068. In the title compound, 1D [H₂Mo₄O₁₄]_n^2n- chains are linked by the Zn²⁺ ions to form 2D inorganic bimetallic layer [Zn(H₂Mo₄O₁₄)]_n. The adjacent 2D layers are further connected by the bridging ligands 3-bpye to construct 3D framework with CdSO₄ topology. This zinc compound possesses strong fluorescence emission. Moreover, this compound shows remarkable photocatalytic activities for the degradation of methylene blue and rhodamine B under ultraviolet irradiation. CCDC: 1493115.
- polyoxomolybdate,
- bis(pyridyl)-bis(amide) ligand,
- zinc compound,
- crystal structure,
- fluorescent property,
- photocatalytic activity
1. [1]
  Guo Z Y, Song X Z, Lei H P. A Ketone Functionalized Luminescent Terbium Metal-Organic Framework for Sensing of Small Molecules[J]. Chem Commun, 2015,51(2):376-379. doi: 10.1039/C4CC06729K
2. [2]
  Mondloch J E, Karagiaridi O, Farha O K. Activation of Metal Organic Framework Materials[J]. CrystEngComm, 2013,15(45):9258-9264. doi: 10.1039/c3ce41232f
3. [3]
  Wu P Y, Jiang M, Hu X F. Amide-containing Luminescent Metal Organic Complexes as Bifunctional Materials for Selective Sensing of Amino Acids and Reaction Prompting[J]. RSC Adv, 2016,6(33):27944-27951. doi: 10.1039/C5RA27806F
4. [4]
  Sha J Q, Sun J W, Z hu. The First Two-fold Interpenetrating Polyoxometalate-based Coordination Polymer with Helical Channels:Structure and Catalytic Activities[J]. CrystEngComm, 2016,18(2):283-289. doi: 10.1039/C5CE02021B
5. [5]
  Wang Y, Sun X P, Li S Z. Generation of Large Polynuclear Rare Earth Metal-Containing Organic Inorganic Polytungstoarsenate Aggregates[J]. Cryst Growth Des, 2015,15(5):2057-2063. doi: 10.1021/cg5012499
6. [6]
  Xu S S, Chen W L, Wang Y H. Co-sensitization Promoted Light Harvesting with a New Mixed-addenda Polyoxometalate[Cu(C₁₂H₈N₂)₂]₂[V₂W₄O₁₉]·4H₂O in Dye-sensitized Solar Cells[J]. Dalton Trans, 2015,44(42):18553-18562. doi: 10.1039/C5DT02992A
7. [7]
  Fu H, Qin C, Lu Y. An Ionothermal Synthetic Approach to Porous Polyoxometalate-Based Metal Organic Frameworks[J]. Angew Chem, 2012,124(32):8109-8113. doi: 10.1002/ange.201202994
8. [8]
  Lan Y Q, Li S L, Wang X L. Selfassembly of Polyoxometalate-based Metal Organic Frameworks Based on Octamolybdates and Copper-organic Units:From Cu^Ⅱ, Cu^{Ⅰ, Ⅱ} to Cu^Ⅰ via Changing Organic Amine[J]. Inorg Chem, 2008,47(18):8179-8187. doi: 10.1021/ic800702d
9. [9]
  Du X D, Li C H, Zhang Y. Coordination Polymers Based on the Octamolybdate and Flexible Bis(triazole) Ligands with Different Spacer Lengths[J]. CrystEngComm, 2011,13(7):2350-2357. doi: 10.1039/c0ce00517g
10. [10]
  Kan W Q, Yang J, Liu Y Y. Series of Inorganic Organic Hybrid Materials Constructed From Octamolybdates and Metal Organic Frameworks:Syntheses, Structures, and Physical Properties[J]. Inorg Chem, 2012,51(21):11266-11278. doi: 10.1021/ic300134z
11. [11]
  Zhang C J, Pang H J, Tang Q. Tailoring Microstructures of Isopolymolybdates:Regular Tuning of the Ligand Spacer Length and Metal Coordination Preferences[J]. Dalton Trans, 2010,39(34):7993-7999. doi: 10.1039/c002037k
12. [12]
  Yang M X, Lin S, Chen L J. Two Novel 3D Bimetallic Oxide Framework with 16-Membered Wheel Clusters Based on {Mo₅O₁₆} Ribbon-like Chains[J]. Inorg Chem Commun, 2011,14:1652-1655. doi: 10.1016/j.inoche.2011.06.031
13. [13]
  Liu H Y, Wu H, Yang J. pH-Dependent Assembly of 1D to 3D Octamolybdate Hybrid Materials Based on a New Flexible Bis-[(pyridyl)-benzimidazole] Ligand[J]. Cryst Growth Des, 2011,11(5):2920-2927.
14. [14]
  Chen Y Q, Li G R, Qu Y K. Water-Insoluble Heterometal-Oxide-Based Photocatalysts Effective for the Photo-Decomposition of Methyl Orange[J]. Cryst Growth Des, 2013,13(2):901-907. doi: 10.1021/cg3016244
15. [15]
  Chen H L, Li M X, He X. Seven Organic Inorganic Hybrid Compounds Constructed from 2, 4, 6-Tris-(pyridyl)-1, 3, 5-triazine and Polyoxometalates[J]. Inorg Chim Acta, 2010,36:3186-3193.
16. [16]
  Lin H Y, Xu C, Wang X L. Two isostructural 3D Metal-Organic Frameworks Constructed from 1D[H₂Mo₄O₁₄]_n^2n- Chains and the Flexible Bis-pyridyl-bis-amide Ligand[J]. Inorg Chem Commun, 2013,36:81-85. doi: 10.1016/j.inoche.2013.08.020
17. [17]
  Wang X L, Sun J J, Lin H Y. Novel Anderson-type[TeMo₆O₂₄]^6--based Metal-organic Complexes Tuned by Different Species and Their Coordination Modes:Assembly, Various Architectures and Properties[J]. Dalton Trans, 2016,45(6):2709-2719. doi: 10.1039/C5DT04074D
18. [18]
  Wang X L, Chang Z H, Lin H Y. Effect of Polyoxoanions and Amide Group Coordination Modes on the Assembly of Polyoxometalate-based Metal-organic Complexes Constructed from a Semi-rigid Bis-pyridyl-bis-amide Ligand[J]. CrystEngComm, 2015,17(4):895-903. doi: 10.1039/C4CE01933D
19. [19]
  Wang X L, Chang Z H, Lin H Y. Assembly and photocatalysis of Two Novel 3D Anderson-type Polyoxometalate-based Metal-organic Frameworks Constructed from Isomeric Bis(pyridylformyl)piperazine Ligands[J]. Dalton Trans, 2014,43(32):12272-12278. doi: 10.1039/C4DT01211A
20. [20]
  Wang X L, Sun J J, Lin H Y. A series of Anderson-type Polyoxometalate-based Metal-organic Complexes:Their pH-Dependent Electrochemical Behaviour, and as Electrocatalysts and Photocatalysts[J]. Dalton Trans, 2016,45(31):12465-12478. doi: 10.1039/C6DT02216B
21. [21]
  LIN Hongyan, ZENG Ling, WANG Qinglin. Synthesis, Structure and Catalytic Properties of the Keggin-type Silicomolybdenate-based Silver Compound Modified by a Bis-pyridyl-bis-amide Ligand[J]. Chinese J Appl Chem, 2016,33(1):76-83. doi: 10.11944/j.issn.1000-0518.2016.01.150199
22. [22]
  Muthu S, Yip J H K, Vittal J J. Coordination Networks of Ag(Ⅰ) and N, N'-Bis(3-pyridinecarboxamide)-1, 6-hexane:Structures and Anion Exchange[J]. J Chem Soc, Dalton Trans, 2002(24):4561-4568. doi: 10.1039/B206680G
23. [23]
  Brown I D, Altermatt D. Bond-valence Parameters Obtained from a Systematic Analysis of the Inorganic Crystal Structure Database[J]. Acta Crystallogr, Sect B, 1985,41(4):244-247. doi: 10.1107/S0108768185002063
24. [24]
  Dong B X, Xu Q. Investigation of Flexible Organic Ligands in the Molybdate System:Delicate Influence of a Peripheral Cluster Environment on the Isopolymolybdate Frameworks[J]. Inorg Chem, 2009,48(13):5861-5873. doi: 10.1021/ic900128t
25. [25]
  Adarsh N N, Dastidar P. A New Series of Zn^Ⅱ Coordination Polymer Based Metallogels Derived from Bis-pyridyl-bis-amide Ligands:A Crystal Engineering Approach[J]. Cryst Growth Des, 2011,11(1):328-336. doi: 10.1021/cg101342g
26. [26]
  Dutta D, Jana A D, Debnath M. Robust 1D Open Rack-like Architecture in Coordination Polymers of Anderson POMs[{Na₄(H₂O)₁₄}{Cu(gly)}₂] [TeMo₆O₂₄] and[{Cu(en)₂}₃{TeW₆O₂₄}]:Synthesis, Characterization and Heterogeneous Catalytic Epoxidation of Olefines[J]. Dalton Trans, 2010,39(48):11551-11559. doi: 10.1039/c0dt00426j
27. [27]
  Xu C Y, Li L K, Wang Y P. Three-dimensional Cd(Ⅱ) Coordination Polymers Based on Semirigid Bis(methylbenzimidazole) and Aromatic Polycarboxylates:Syntheses, Topological Structures and Photoluminescent Properties[J]. Cryst Growth Des, 2011,11(10):4667-4675. doi: 10.1021/cg200961a
28. [28]
  Li S B, Zhang L, O'Halloran K P. An Unprecedented 3D POM-MOF Based on (7, 8)-Connected Twin Wells-Dawson Clusters:Synthesis, Structure, Electrocatalytic and Photocatalytic Properties[J]. Dalton Trans, 2015,44(6):2062-2065.
29. [29]
  Wang X L, Han N, Lin H Y. pH and Amine-induced Various Octamolybdate-based Metal-organic Complexes:Assembly, Structures and Properties[J]. Dalton Trans, 2014,43(5):2052-2060. doi: 10.1039/C3DT52494A
1. [1]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
2. [2]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
3. [3]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
4. [4]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
5. [5]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
6. [6]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
7. [7]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
8. [8]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
9. [9]
  Ruiying WANG , Hui WANG , Fenglan CHAI , Zhinan ZUO , Benlai WU . Three-dimensional homochiral Eu(Ⅲ) coordination polymer and its amino acid configuration recognition. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 877-884. doi: 10.11862/CJIC.20250052
10. [10]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
11. [11]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
12. [12]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
13. [13]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
14. [14]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
15. [15]
  Linjie ZHU , Xufeng LIU . Synthesis, characterization and electrocatalytic hydrogen evolution of two di-iron complexes containing a phosphine ligand with a pendant amine. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 939-947. doi: 10.11862/CJIC.20240416
16. [16]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
17. [17]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
18. [18]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
19. [19]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
20. [20]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(281)
HTML views(39)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

A Three-Dimensional Zinc Compound Based on One-Dimensional [H2Mo4O14]n2n- Chain and Bis(pyridyl)-Bis(amide) Ligand: Synthesis, Structure and Property

Metrics

通讯作者: 陈斌, bchen63@163.com

A Three-Dimensional Zinc Compound Based on One-Dimensional [H₂Mo₄O₁₄]_n^2n- Chain and Bis(pyridyl)-Bis(amide) Ligand: Synthesis, Structure and Property