Citation: XIE Dandan, YAN Liang, YIN Yuli, ZHANG Zhaohui, WANG Jing. Preparation and Application of Magnetic Multi-ion Imprinted Polymers Based on Multiwalled Carbon Nanotubes[J]. Chinese Journal of Applied Chemistry, ;2017, 34(4): 456-463. doi: 10.11944/j.issn.1000-0518.2017.04.160268 shu

Preparation and Application of Magnetic Multi-ion Imprinted Polymers Based on Multiwalled Carbon Nanotubes

XIE Dandan ^a ,
YAN Liang ^a ,
YIN Yuli ^a,b ,
ZHANG Zhaohui ^a,b,c,*,, ,
WANG Jing ^a,b

a.
College of Chemistry and Chemical Engineering, Jishou University, Jishou, Hu'nan 416000, China
b.
Key Laboratory of Mineral Cleaner Production and Exploit of Green Functional Materials in Hu'nan Province, Jishou University, Jishou, Hu'nan 416000, China
c.
State Key Laboratory of Chemo Biosensing and Chemometrics, Hu'nan University, Changsha 410082, China

Corresponding author: ZHANG Zhaohui, zhaohuizhang77@163.com
Received Date: 29 June 2016
Revised Date: 9 October 2016
Accepted Date: 16 November 2016

Fund Project: the National Natural Science Foundation of China 21267010Open Foundation of Hunan Province Laboratory of Mineral Cleaner Production and Green Functional Materials, and Science MCPEGFM-200602the National Natural Science Foundation of China 21565014

Figures(8)

Novel magnetic multi-ion imprinted polymers (MⅡPs) were synthesized using magnetic multi-walled carbon nanotubes as the supporting materials, Co²⁺, Cu²⁺ and Cd²⁺ as the multi-template and dopamine as the functional monomer. The MⅡPs were characterized with Fourier-transform infrared spectrometry, transmission electron microscope, scanning electron microscope and vibrating sample magnetometer in details. Adsorption performance of the MⅡPs was investigated by magnetic solid phase extraction and atomic absorption spectroscopy. The results reveal that the MⅡPs have outstanding magnetic property, high adsorption capacity, high selectivity and fast binding kinetics toward Cu²⁺, Co²⁺and Cd²⁺ with the maximum adsorption capacity of 46.08 mg/g, 36.35 mg/g and 30.65 mg/g, respectively. Combined with atomic absorption spectroscopy, MⅡPs were successfully used to separate and enrich Cu²⁺, Co²⁺and Cd²⁺ in real sludge samples with the enrichment factor of 18.6, 13.4 and 10.9, respectively.
- magnetic multi-ion imprinted polymers,
- polydopamine,
- heavy metal ion,
- magnetic solid phase extraction
1. [1]
  PENG Yuanzhen, HUANG Yongming, YUAN Dongxing. Rapid Analysis of Heavy Metal Ions in Coastal Seawater Using Preconcentration with Precipitation/Co-precipitation on Membrane and Detection with X-Ray Fluorescence[J]. Chinese J Anal Chem, 2012,40(6):877-882.
2. [2]
  JIANG Qiutao, ZENG Li, MA Jie. Determination of Soluble Heavy Metals in Baizi Yangxin Tablets by Inductively Coupled Plasma Mass Spectrometry with Bionic Extraction and Microwave Digestion Technology[J]. Chinese J Anal Chem, 2016,44(6):979-983.
3. [3]
  AN Huiqin, ZHU Baolin, WU Hongyan. Synthesis and Characterization of Titanate and CS₂-modified Titanate Nanotubes as Well as Their Adsorption Capacities for Heavy Metal Ions[J]. Chem J Chinese Univ, 2008,29(3):439-444.
4. [4]
  Vlatakis G, Andersson LI, Muller R. Drug Assay Using Antibody Mimics Made by Molecular Imprinting[J]. Nature, 1993,361(2):645-647.
5. [5]
  Peng W, Xie Z Z, Cheng G. Amino-Functionalized Adsorbent Prepared by Means of Cu (Ⅱ) Imprinted Method and Its Selective Removal of Copper from Aqueous Solutions[J]. J Hazard Mater, 2015,294(8):9-16.
6. [6]
  Gao D M, Zhang Z P, Wu M H. A Surface Functional Monomer-Directing Strategy for Highly Dense Imprinting of TNT at Surface of Silica Nanoparticles[J]. J Am Chem Soc, 2007,129(25):7859-7866. doi: 10.1021/ja070975k
7. [7]
  Zhang Z H, Zhang H B, Hu Y F. Synthesis and Application of Multi-walled Carbon Nanotubes-Molecularly Imprinted Sol-Gel Composite Material for On-Line Solid-Phase Extraction and High-Performance Liquid Chromatography Determination of Trace Sudan Ⅳ[J]. Anal Chim Acta, 2010,661(2):173-180. doi: 10.1016/j.aca.2009.12.024
8. [8]
  Pan J M, Xu L C, Dai J D. Magnetic Molecularly Imprinted Polymers Based on Attapulgite/Fe₃O₄ Particles for The Selective Recognition of 2, 4-Dichlorophenol[J]. Chem Eng J, 2011,174(1):68-75. doi: 10.1016/j.cej.2011.08.046
9. [9]
  Bie Z J, Chen Y, Ye J. Boronate-Affinity Glycan-Oriented Surface Imprinting:A New Strategy to Mimic Lectins for the Recognition of an Intact Glycoprotein and Its Characteristic Fragments[J]. Angew Chem, 2015,127(7):10349-10353.
10. [10]
  Tan C J, Tong Y W. Preparation of Superparamagnetic Ribonuclease A Surface-Imprinted Submicrometer Particles for Protein Recognition in Aqueous Media[J]. Anal Chem, 2007,79(1):299-306. doi: 10.1021/ac061364y
11. [11]
  Bi X D, Liu Z. Facile Preparation of Glycoprotein-Imprinted 96-Well Microplates for Enzyme-Linked Immunosorbent Assay by Boronate Affinity-Based Oriented Surface Imprinting[J]. Anal Chem, 2014,86(1):959-966. doi: 10.1021/ac403736y
12. [12]
  Zhang M, Wang Y Z, Jia X P. The Preparation of Magnetic Molecularly Imprinted Nanoparticles for the Recognition of Bovine Hemoglobin[J]. Talanta, 2014,120(3):376-385.
13. [13]
  Li S W, Yang K G, Liu J X. Surface-Imprinted Nanoparticles Prepared with a His-Tag-Anchored Epitope as the Template[J]. Anal Chem, 2015,87(9):4617-4620. doi: 10.1021/ac5047246
14. [14]
  Xia Z W, Lin Z, Xiao Y. Polydopamine-Coated Molecularly Imprinted Silica Nanoparticles for Protein Recognition and Separation[J]. Biosens Bioelectron, 2013,47(9):120-126.
15. [15]
  Wang S S, Ye J, Bie Z J. Affinity-Tunable Specific Recognition of Glycoproteins via Boronate Affinity-Based Controllable Oriented Surface Imprinting[J]. Chem Sci, 2014,5(12):1135-1140.
16. [16]
  YIN Yuli, LONG Fang, RAO Wei. Preparation and Adsorption Properties of Novel Magnetic Nonylphenol Molecularly Imprinted Nanocomposite Material Based on Multiwalled Carbon Nanotubes[J]. Chinese J Appl Chem, 2015,32(4):472-480. doi: 10.11944/j.issn.1000-0518.2015.04.140254
17. [17]
  Xiao D L, Yuan D H, He H. Mixed Hemimicelle Solid-Phase Extraction Based on Magnetic Carbon Nanotubes and Ionic Liquids for the Determination of Flavonoids[J]. Carbon, 2014,72(6):274-286.
18. [18]
  Zhang M, Huang J, Yu P. Preparation and Characteristics of Protein Molecularly Imprinted Membranes on the Surface of Multiwalled Carbon Nanotubes[J]. Talanta, 2010,81(1):162-166.
19. [19]
  Menezes H C, de Barcelos S M R, Macedo D F D. Magnetic N-Doped Carbon Nanotubes:A Versatile and Efficient Material for the Determination of Polycyclic Aromatic Hydrocarbons in Environmental Water Samples[J]. Anal Chim Acta, 2015,873(5):51-56.
1. [1]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
2. [2]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
3. [3]
  Peiyu Zhang , Aixin Song , Jingcheng Hao , Jiwei Cui . 高频超声法制备聚多巴胺薄膜综合实验. University Chemistry, 2025, 40(6): 210-214. doi: 10.12461/PKU.DXHX202407081
4. [4]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
5. [5]
  Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013
6. [6]
  Yuxia Luo , Xiaoyu Xie , Fangfang Chen . 药物递送魔法师——分子印迹聚合物. University Chemistry, 2025, 40(8): 202-210. doi: 10.12461/PKU.DXHX202409129
7. [7]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
8. [8]
  Wei GUO , Zhuoyi GUO , Xiaoxin LI , Wei ZHANG , Juanzhi YAN , Tingting GUO . Electrochemical sensor based on a Co(Ⅱ)-based metal-organic framework for the detection of Cd²⁺ and Pb²⁺. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1889-1902. doi: 10.11862/CJIC.20250097
9. [9]
  Jia-He Li , Yu-Ze Liu , Jia-Hui Ma , Qing-Xiao Tong , Jian-Ji Zhong , Jing-Xin Jian . 洛芬碱衍生物的合成、化学发光与重金属离子检测. University Chemistry, 2025, 40(6): 230-237. doi: 10.12461/PKU.DXHX202407080
10. [10]
  Yun Chen , Daijie Deng , Li Xu , Xingwang Zhu , Henan Li , Chengming Sun . Covalent bond modulation of charge transfer for sensitive heavy metal ion analysis in a self-powered electrochemical sensing platform. Acta Physico-Chimica Sinica, 2026, 42(1): 100144-0. doi: 10.1016/j.actphy.2025.100144
11. [11]
  Ke Qiu , Fengmei Wang , Mochou Liao , Kerun Zhu , Jiawei Chen , Wei Zhang , Yongyao Xia , Xiaoli Dong , Fei Wang . A Fumed SiO₂-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2304036-0. doi: 10.3866/PKU.WHXB202304036
12. [12]
  Chunyuan Kang , Xiaoyu Li , Fan Yang , Bai Yang . Ionic-bond crosslinked carbonized polymer dots for tunable and enhanced room temperature phosphorescence. Acta Physico-Chimica Sinica, 2026, 42(1): 100156-0. doi: 10.1016/j.actphy.2025.100156
13. [13]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
14. [14]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
15. [15]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
16. [16]
  Xuefei Leng , Yanshai Wang , Hai Wang , Shengyang Tao . The In-Depth integration of “Industry-University-Research” in the Exploration and Practice of “Comprehensive Training in Polymer Engineering”. University Chemistry, 2025, 40(4): 66-71. doi: 10.12461/PKU.DXHX202405105
17. [17]
  Ruiying WANG , Hui WANG , Fenglan CHAI , Zhinan ZUO , Benlai WU . Three-dimensional homochiral Eu(Ⅲ) coordination polymer and its amino acid configuration recognition. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 877-884. doi: 10.11862/CJIC.20250052
18. [18]
  Minghui Wu , Markus Mühlinghaus , Xuechao Li , Chaojie Xu , Qiang Chen , Haiming Zhang , Klaus Müllen , Lifeng Chi . On-Surface Synthesis of Chevron-Shaped Conjugated Ladder Polymers Consisting of Benzo[a]azulene Units. Acta Physico-Chimica Sinica, 2024, 40(8): 2307024-0. doi: 10.3866/PKU.WHXB202307024
19. [19]
  Ye Wang , Ruixiang Ge , Xiang Liu , Jing Li , Haohong Duan . An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol. Acta Physico-Chimica Sinica, 2024, 40(7): 2307019-0. doi: 10.3866/PKU.WHXB202307019
20. [20]
  Fanpeng Meng , Fei Zhao , Jingkai Lin , Jinsheng Zhao , Huayang Zhang , Shaobin Wang . Optimizing interfacial electric fields in carbon nitride nanosheet/spherical conjugated polymer S-scheme heterojunction for hydrogen evolution. Acta Physico-Chimica Sinica, 2025, 41(8): 100095-0. doi: 10.1016/j.actphy.2025.100095

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(726)
HTML views(87)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142