Citation: CHEN Peizhen, LIU Ruilai, RAO Ruiye. Synthesis and Characterization of Poly(N-isopropyl acrylamide)-g-cellulose Hydrogels[J]. Chinese Journal of Applied Chemistry, ;2016, 33(12): 1389-1395. doi: 10.11944/j.issn.1000-0518.2016.12.160216 shu

Synthesis and Characterization of Poly(N-isopropyl acrylamide)-g-cellulose Hydrogels

CHEN Peizhen ^a ,
LIU Ruilai ^a,b,, ,
RAO Ruiye ^a

1.
a College of Ecological and Resource Engineering, Fujian Provincial Key Laboratory of Eco-Industrial Green Technology, Wuyi University, Wuyishan, Fujian 354300, China;
2.
b College of Material Science and Engineering, Fujian Normal University, Fuzhou 350007, China

Corresponding author: LIU Ruilai,
Received Date: 24 May 2016
Available Online: 7 July 2016
Fund Project:

Thermally-responsive PNIPAm-g-cellulose nanofibers hydrogels were prepared by thermally-responsive poly(N-isopropyl acrylamide)(PNIPAm) grafted electrospun cellulose nanofibrous membranes. The effect of mass ratio of monomer and cellulose, reaction temperature, reaction time and amounts of initiator on grafting rate, swelling rate and morphology were investigated. The results show that the optimum reaction condition are as follows:mass ratio of monomer and cellulose in 15:1, reaction temperature at 40℃, reaction time for 3 h and initiator concentration of 10 mmol/L, the grafting rate and swelling rate of PNIPAm-g-Cell at 35% and 31%, respectively. Compared with PNIPAm hydrogels, the lower critical solution temperature(LCST) of PNIPAm-g-Cell hydrogels is obviously increased, indicating that hydrophilic-hydrophobic balance was changed by adding hydrophilic cellulose. Deswelling kinetics of the PNIPAm-g-Cell hydrogels shows that water-retention rate is decreased to 93% and 61% for grafting rate of 25% and 35%, respectively, in initiatory 0.5 min. PNIPAm-g-Cell hydrogels with high grafting rate have greater sensitivity to temperature.
- cellulose,
- poly(N-isopropyl acrylamide),
- grafting,
- thermally-responsive,
- hydrogels
1. [1]
  [1] Zhu Y,Jiang H,Ye S H,et al. Tailoring the Degradation Rates of Thermally Responsive Hydrogels Designed for Soft Tissue Injection by Varying the Autocatalytic Potential[J]. Biomaterials,2015,53(7):484-493.
2. [2]
  [2] FENG Qiao,ZHANG Yaxuan,XIA Zhiwei,et al. Frontal Polymerization and Characterization of Poly(N-isopropylacrylamide-co-N-vinyl-2-pyrrolidone) Hydrogels[J]. Polym Mater Sci Eng,2015,31(4):37-41(in Chinese).冯巧,张亚轩,夏志伟,等. 温敏型水凝胶聚(N-异丙基丙烯酰胺-乙烯基吡咯烷酮)的前端聚合法制备及性能[J]. 高分子材料科学与工程,2015,31(4):37-41.
3. [3]
  [3] Rzaev Z M,Dincer S,Piskin E. Functional Copolymers of N-Isopropylacrylamide for Bioengineering Applications[J]. Prog Polym Sci,2007,32(5):534-595.
4. [4]
  [4] Galperin A,Long T J,Garty S,et al. Synthesis and Fabrication of a Degradable Poly(N-isopropyl acrylamide) Scaffold for Tissue Engineering Applications[J]. J Biomed Mater Res Part A,2013,101(3):775-786.
5. [5]
  [5] Li L,Hsieh Y L. Ultra-fine Polyelectrolyte Hydrogel Fibres from Poly(acrylic acid)/Poly(vinyl alcohol)[J]. Nanotechnology,2005,16(12):2852-2860.
6. [6]
  [6] Li L,Hsieh Y L. Ultra-fine Polyelectrolyte Fibers from Electrospinning of Poly(acrylic acid)[J]. Polymer,2005,46(14):5133-5139.
7. [7]
  [7] LIU Ruilai,LIU Junshao,LIU Haiqing. Fabrication of PLLA/CA Composites Porous Ultrafine Fibers[J]. Acta Polym Sin,2013,(10):1312-1318(in Chinese).刘瑞来,刘俊劭,刘海清. 聚乳酸/醋酸纤维素复合多孔超细纤维的制备[J]. 高分子学报,2013,(10):1312-1318.
8. [8]
  [8] Cao S G,Hu B H,Liu H Q. Synthesis of pH-responsive Crosslinked Poly[styrene-co-(maleic sodium anhydride)] and Cellulose Composite Hydrogel Nanofibers by Electrospinning[J]. Polym Int,2009,58(2):545-551.
1. [1]
  Xiaojing Tian , Zhichun Huang , Qingsong Zhang , Xu Wang , Ning Yang , Nanping Deng . PNIPAm Thermo-Responsive Nanofibers Mats: Morphological Stability and Response Behavior under Cross-Linking. Acta Physico-Chimica Sinica, 2024, 40(4): 2304037-0. doi: 10.3866/PKU.WHXB202304037
2. [2]
  Qiang Zhou , Pingping Zhu , Wei Shao , Wanqun Hu , Xuan Lei , Haiyang Yang . Innovative Experimental Teaching Design for 3D Printing High-Strength Hydrogel Experiments. University Chemistry, 2024, 39(6): 264-270. doi: 10.3866/PKU.DXHX202310064
3. [3]
  Qingyang Cui , Feng Yu , Zirun Wang , Bangkun Jin , Wanqun Hu , Wan Li . From Jelly to Soft Matter: Preparation and Properties-Exploring of Different Kinds of Hydrogels. University Chemistry, 2024, 39(9): 338-348. doi: 10.3866/PKU.DXHX202309046
4. [4]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
5. [5]
  Yan'e LIU , Shengli JIA , Yifan JIANG , Qinghua ZHAO , Yi LI , Xinshu CHANG . MoO₃/cellulose derived carbon aerogel: Fabrication and performance as cathode for lithium-sulfur battery. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1565-1573. doi: 10.11862/CJIC.20250054
6. [6]
  Zhongrui Wang , Yuwen Meng , Xu Wang . 双层水凝胶的制备及其pH响应变形实验. University Chemistry, 2025, 40(8): 255-264. doi: 10.12461/PKU.DXHX202410038
7. [7]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
8. [8]
  Lisha LEI , Wei YONG , Yiting CHENG , Yibo WANG , Wenchao HUANG , Junhuan ZHAO , Zhongjie ZHAI , Yangbin DING . Application of regenerated cellulose and reduced graphene oxide film in synergistic power generation from moisture electricity generation and Mg-air batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1151-1161. doi: 10.11862/CJIC.20240202
9. [9]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-0. doi: 10.3866/PKU.WHXB202403005
10. [10]
  Tengjiao Wang , Tian Cheng , Rongjun Liu , Zeyi Wang , Yuxuan Qiao , An Wang , Peng Li . Conductive Hydrogel-based Flexible Electronic System: Innovative Experimental Design in Flexible Electronics. University Chemistry, 2024, 39(4): 286-295. doi: 10.3866/PKU.DXHX202309094
11. [11]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368
12. [12]
  Ke Qiu , Fengmei Wang , Mochou Liao , Kerun Zhu , Jiawei Chen , Wei Zhang , Yongyao Xia , Xiaoli Dong , Fei Wang . A Fumed SiO₂-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2304036-0. doi: 10.3866/PKU.WHXB202304036
13. [13]
  Tengyue ZHANG , Jingjing FENG , Zili LIANG , Jia′nan DAI , Jing MA . Optimization of C-doped BiVO₄ performance for tetracycline degradation using response surface methodology-assisted orthogonal experiments. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2561-2574. doi: 10.11862/CJIC.20250104
14. [14]
  Hongyun Liu , Jiarun Li , Xinyi Li , Zhe Liu , Jiaxuan Li , Cong Xiao . Course Ideological and Political Design of a Comprehensive Chemistry Experiment: Constructing a Visual Molecular Logic System Based on Intelligent Hydrogel Film Electrodes. University Chemistry, 2024, 39(2): 227-233. doi: 10.3866/PKU.DXHX202309070
15. [15]
  Lijuan Liu , Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 313-318. doi: 10.12461/PKU.DXHX202403060
16. [16]
  Caixia Lin , Ting Liu , Zhaojiang Shi , Hong Yan , Keyin Ye , Yaofeng Yuan . Innovative Experiment of Electrochemical Dearomative Spirocyclization of N-Acyl Sulfonamides. University Chemistry, 2025, 40(4): 359-366. doi: 10.12461/PKU.DXHX202406107
17. [17]
  Xichen YAO , Shuxian WANG , Yun WANG , Cheng WANG , Chuang ZHANG . Oxygen reduction performance of self?supported Fe/N/C three-dimensional aerogel catalyst layers. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1387-1396. doi: 10.11862/CJIC.20240384
18. [18]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-0. doi: 10.3866/PKU.WHXB202408012
19. [19]
  Wanchun Zhu , Yongmei Liu , Li Wang , Yunshan Bai , Shu'e Song , Xiaokui Wang , Zhongyun Wu , Hong Yuan , Yunchao Li , Fuping Tian , Yuan Chun , Jianrong Zhang , Shuyong Zhang . Suggestions on Operating Specifications of Physical Chemistry Experiment: Measurement and Control of Temperature. University Chemistry, 2025, 40(5): 128-136. doi: 10.12461/PKU.DXHX202503028
20. [20]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(783)
HTML views(191)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142