Citation: YUAN Senwen, ZHAO Lang, LI Hongtao. Synthesis and Characterization of Magnetic and Fluorescent Bifunctional Fe₃O₄@SiO₂@ZrO₂：Tb³⁺ Spherical Nanocomposites[J]. Chinese Journal of Applied Chemistry, ;2016, 33(8): 968-976. doi: 10.11944/j.issn.1000-0518.2016.08.150396 shu

Synthesis and Characterization of Magnetic and Fluorescent Bifunctional Fe₃O₄@SiO₂@ZrO₂：Tb³⁺ Spherical Nanocomposites

YUAN Senwen ^a,b ,
ZHAO Lang ^b,, ,
LI Hongtao ^a,,

1.
a School of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, China;
2.
b State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Corresponding author: ZHAO Lang, LI Hongtao,
Received Date: 10 November 2015
Available Online: 24 December 2015
Fund Project: 国家自然科学基金项目(21201160)；黑龙江大学功能无机材料化学教育部重点实验室开放基金 (21201160)

New water-soluble magnetic and fluorescent Fe₃O₄@SiO₂@ZrO₂:Tb³⁺ nanocomposites(NCs) have been successfully synthesized through the in situ synthesized method. The morphology, size, phase, magnetic properties and fluorescent properties of as-synthesized nanoparticles(NPs) were well investigated by scanning electron microscopy(SEM), X-ray diffraction(XRD), Fourier transform infrared spectroscopy(FT-IR), magnetometer, and photoluminescence(PL) spectra. The magnetic and fluorescent NPs consist of silica-coated Fe₃O₄ as the core and the ZrO₂:Tb³⁺ as the shell exhibit superparamagnetism with the saturation magnetization of 36 emu/g and fluorescence properties with four emission bands peaked at approximately 494 nm(⁵D₄→⁷F₆), 549 nm(⁵D₄→⁷F₅), 587 nm(5D ₄→⁷F₄), and 625 nm(⁵D₄→⁷F₃) of Tb³⁺ ions. The bifunctional magnetic and fluorescence NCs will show potential applications in biomedical fields in the future.
- water-soluble,
- bifunctional,
- magnetic and fluorescent
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Synthesis and Characterization of Magnetic and Fluorescent Bifunctional Fe₃O₄@SiO₂@ZrO₂：Tb³⁺ Spherical Nanocomposites