Citation: WANG Jiaoliang, LONG Liping, XIE Dan. A Coumarin 343 Basded Fluorescent Probe for Fast Sensing of Sulfite Ion[J]. Chinese Journal of Applied Chemistry, ;2016, 33(7): 841-847. doi: 10.11944/j.issn.1000-0518.2016.07.150348 shu

A Coumarin 343 Basded Fluorescent Probe for Fast Sensing of Sulfite Ion

1.
College of Chemistry and Environment Engineering, Hu'nan City University, Yiyang, Hu'nan 413000, China

Corresponding author: WANG Jiaoliang,
Received Date: 28 September 2015
Available Online: 12 January 2016
Fund Project:

The probe, Coumarin 343-SO₂, was readily synthesized from Coumarin 343 and 2-benzothiazole acetonitrile. The structure of this probe was fully characterized by ¹H NMR, ¹³C NMR, MS, and HRMS. The mechanism of this fluorescent probes for SO₃^2- is based on blocking conjugated structure of the benzothiazole and coumarin upon SO₃^2- nucleophilic addition. The probe exhibits excellent water solubility, fast response, high sensitivity, and high selectivity over other biological related species, with the low detection limit at 0.08 μmol/L. In addition, the probe has good cell membrane permeability, and is suitable for fluorescence imaging of SO₃^2- in living cells.
- coumarin 343,
- fluorescence probe,
- sulfite ion,
- cell imaging
1. [1]
  [1] Pizzoferrato L,Di Lullo G,Quattrucci E. Determination of Free, Bound and Total Sulfites in Foods by Indirect Photometry-HPLC[J]. Food Chem,1998,63(2):275-279.
2. [2]
  [2] Araujo A N,Couto C M C M,Lima J L F C,et al. Determination of SO₂ in Wines Using a Flow Injection Analysis System with Potentiometric Detection[J]. J Agric Food Chem,1998,46(1):168-172.
3. [3]
  [3] Lowinsohn D,Bertotti M. Determination of Sulphite in Wine by Coulometric Titration[J]. Food Addit Contam,2001,18(9):773-777.
4. [4]
  [4] Silva K R B,Raimundo I M J,Gimenez I F,et al. Optical Sensor for Sulfur Dioxide Determination in Wines[J]. J Agric Food Chem,2006,54(23):8697-8701.
5. [5]
  [5] Koch M,Koeppen R,Siegel D,et al. Determination of Total Sulfite in Wine by Ion Chromatography after In-Sample Oxidation[J]. J Agric Food Chem,2010,58(17):9463-9467.
6. [6]
  [6] ZHANG shuihua,et al. Food Analysis[M]. Beijing:China Light Industry Press,1994,326(in Chinese).张水华,等. 食品分析[M]. 北京:中国轻工业出版社,1994:326.
7. [7]
  [7] Stonys D B. Determination of Sulfur Dioxide in Foods by Modified Monier-Williams Distillation and Polarographic Detection[J]. J Assoc Off Anal Chem,1987,70(1):114-117.
8. [8]
  [8] Sakchai S,Pornthana P,Saisunee L. Preparition Flow Injection Analysis for the Determination of Sulphite in Food Samples Utilizing Potassium Permanganate-rhodamine B Chemiluminesce Detection[J]. Food Chem,2010,121(3):893-898.
9. [9]
  [9] Miura Y,Fujisaki M,Haddad P R. Spectrophotometric Determination of Sulfide in the Presence of Sulfite and Thiosulfate via the Precipitation of Bismuth(Ⅲ) Sulfide[J]. Anal Sci,2004,20(2):363-367.
10. [10]
  [10] Malakootian M,Beitollah H,Biparva P. Nanostructured Base Electrochemical Sensor for Determination of Sulfite[J]. Int J Electrochem Sci,2014,9(1):327-341.
11. [11]
  [11] de Macedo A N,Macri J,Belostotsky V,et al. Strong Anion Determination in Biological Fluids by Capillary Electrophoresis for Clinical Diagnostics[J]. Anal Chem,2013,85(22):11112-11120.
12. [12]
  [12] Sun Y Q,Liu J,Zhang J,et al. Fluorescent Probe for Biological Gas SO₂ Derivatives Bisulfite and Sulfite[J]. Chem Commun,2013,49(26):2637-2639.
13. [13]
  [13] Gu X,Liu C,Zhu Y,et al. A Boron-dipyrromethene-based Fluorescent Probe for Colorimetric and Ratiometric Detection of Sulfite[J]. J Agric Food Chem,2011,59(22):11935-11939.
14. [14]
  [14] Wu M Y,He T,Li K,et al. A Real-time Colorimetric and Ratiometric Fluorescent Probe for Sulfite[J]. Analyst,2013,138(10):3018-3025.
15. [15]
  [15] Sun Y,Wang P,Liu J,et al. A Fluorescent Turn-on Probe for Bisulfite Based on Hydrogen Bond-inhibited CN Isomerization Mechanism[J]. Analyst,2012,137(15):3430-3433.
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沈阳化工大学材料科学与工程学院沈阳 110142