Citation: CHEN Lidong, LIU Di, NIU Siqi, JIANG Chunjie, LIU Liping, WANG Xiangsheng, ZHU Jiang. Oxidative Desulfurization of Organic Sulfides over Phosphotungstic Acid/Nano-ZSM-5 Composite Catalyst[J]. Chinese Journal of Applied Chemistry, ;2016, 33(3): 364-366. doi: 10.11944/j.issn.1000-0518.2016.03.150339 shu

Oxidative Desulfurization of Organic Sulfides over Phosphotungstic Acid/Nano-ZSM-5 Composite Catalyst

CHEN Lidong ^a,, ,
LIU Di ^a ,
NIU Siqi ^a ,
JIANG Chunjie ^a ,
LIU Liping ^b ,
WANG Xiangsheng ^b ,
ZHU Jiang ^a,,

a.
a. Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 110629, China;
b.
b. School of Chemistry Engineering, Dalian University of Technology, Dalian, Liaoning 110624, China

Corresponding author: CHEN Lidong, ZHU Jiang,
Received Date: 18 September 2015
Available Online: 26 October 2015
Fund Project:

The phosphotungstic acid(HPW)/nano-ZSM-5 catalyst was prepared by the impregnation method. When the nano-ZSM-5 is supported by HPW alone, the Keggin structure HPW changes to a Dawson structure heteropoly compounds, and the Keggin structure remains unchanged after binding with nickel salt. With oxidative desulfurization of organic sulfides as a probe, the oil desulfurization rate in simulation oils with dibenzothiophene components of n-octane reaches 94.5% at 40℃.
- phosphotungstic acid,
- nano-ZSM-5 zeolite,
- oxidative desulfurization,
- n-octane
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