Citation: CHENG Zhenhua, CUI Na, SONG Zhaoyang, JIANG Shengjuan, ZHU Lijun, XIA Daohong. Aggreation Behavior and Catalytic Sweetening Performance of Sulfonated Metallophthalocyanines[J]. Chinese Journal of Applied Chemistry, ;2016, 33(2): 155-160. doi: 10.11944/j.issn.1000-0518.2016.02.150245 shu

Aggreation Behavior and Catalytic Sweetening Performance of Sulfonated Metallophthalocyanines

1.
State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum, Qingdao, Shandong 266580, China

Corresponding author: XIA Daohong,
Received Date: 13 July 2015
Available Online: 26 October 2015
Fund Project:

Sulfonated metallophthalocyanines are mainly used as oxidation regenerated catalyst in liquefied petroleum gas(LPG) sweetening process. Aggregation behavior of the five sulfonated metallophthalocyanines(MSPc, M=Fe,Co,Ni,Cu,Zn) in the same or different solvents was studied. The influencing factors of inactivation and the influence of aggregation behavior on activity of catalytic oxidation were investigated. The results show that the aggregation of sulfonated metallophthalocyanines is significantly affected by solvents. The aggregation aggravates with the increasing of polarity of the solvent and storage period. Besides, the aggregation of sulfonated metallophthalocyanines is also affected by central metals. The activity of CoSPc and CuSPc catalytic oxidation of thiol is markedly reduced nearly 20% because of the aggregation.
- liquefied petroleum gas sweetening,
- sulfonated metallophthalocyanines,
- aggreation,
- catalytic oxidation desulfurization
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