Citation: CHANG Jing, YAO Hong, WU Hongping, WANG Ruiyue, LIN Qi, WEI Taibao, ZHANG Youming. A Novel Dual-channel Chemosensor for Cyanide Ion in Aqueous Medium[J]. Chinese Journal of Applied Chemistry, ;2016, 33(1): 108-115. doi: 10.11944/j.issn.1000-0518.2016.01.150214 shu

A Novel Dual-channel Chemosensor for Cyanide Ion in Aqueous Medium

1.
School of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730000, China

Corresponding author: ZHANG Youming,
Received Date: 24 June 2015
Available Online: 22 October 2015
Fund Project:

We synthesize a novel sensing molecule 1-hydroxy-naphthalen-ethyl-3-hydroxy-naphthalen-methyl-benzoimidazo-bromate(J1) which can carry out a single selective colorimetric dual-channel recognition of CN^- in aqueous medium. When F^-, Cl^-, Br^-, I^-, AcO^-, HSO₄^-, ClO₄^-, H₂PO₄^-, SCN^- and CN^- ions were added respectively in sensing molecule J1's DMSO/H₂O(3:2 volume ratio) HEPES(pH=7.2) solution, only CN^- turns the solution from colorless to deep yellow. In the same time, only CN^- among the ions added in sensing molecule J1's DMSO/H₂O(4:1, volume ratio) HEPES(pH=7.2) solution allows the chemosensor responding with a dramatic color change, from colorless to bright yellow. These recognition processes are not disturbed by other negative ions. This indicates that sensing molecule J1 is a good colorimetric recognition receptor of CN^-. The UV-Vis spectrum of sensing molecule J1 has a wide linear range over CN^- concentration from 3.875×10^-4 mol/L to 2.15×10^-2 mol/L with a detection limit of 1.575×10^-7 mol/L. The linear range of the fluorescence of the sensor for CN^- is at the concentration from 0.8×10^-4 mol/L to 1.60×10^-3 mol/L with a detection limit of 4.63×10^-6 mol/L. The sensing molecule J1 has good selection, high sensitivity and strong antidisturbance on CN^- in aqueous medium. Based on sensing molecule J1's high selection on CN^-, we specially prepare test paper which can test CN^- in water in a convenient, fast and accurate way.
- acyl hydrazone compounds,
- cyanide ion,
- test paper,
- fluorescent sensor
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