Citation: LIN Hongyan, ZENG Ling, WANG Qinglin, LIU Guocheng, TIAN Yuan. Synthesis, Structure and Catalytic Properties of the Keggin-type Silicomolybdenate-based Silver Compound Modified by a Bis-pyridyl-bis-amide Ligand[J]. Chinese Journal of Applied Chemistry, ;2016, 33(1): 76-83. doi: 10.11944/j.issn.1000-0518.2016.01.150199 shu

Synthesis, Structure and Catalytic Properties of the Keggin-type Silicomolybdenate-based Silver Compound Modified by a Bis-pyridyl-bis-amide Ligand

1.
College of Chemistry and Chemical Engineering, Bohai University, Jinzhou, Liaoning 121013, China

Corresponding author: LIN Hongyan,
Received Date: 15 June 2015
Available Online: 8 October 2015
Fund Project:

A new Keggin-type polyoxometalate-based silver compound constructed from a semi-rigid bis-pyridyl-bis-amide ligand 3-bpcd(N,N'-bis(pyridin-3-yl)cyclohexane-1,4-dicarboxamide), {[Ag₂(3-bpcd)₃] [Ag(3-bpcd)(SiMo₁₂O₄₀)]₂(3-H₂bpcd)₂}·7H₂O was prepared under the hydrothermal condition and characterized by IR, element analysis and X-ray single-crystal diffraction. The title complex is a triclinic system with space group P-1, whose cell parameters are a=1.3597(5) nm, b=1.4949(5) nm, c=2.5249(10) nm, α=88.998(6)°, β=88.856(7)°, γ=67.458(6)°, V=4.739(3) nm³, M_r=6471.02, D_c=2.261g/cm³, Z=1, S=0.955, F(000)=3124, R₁=0.0768, wR₂=0.1936. In this compound, a[Ag(3-bpcd)(SiMo₁₂O₄₀)]₂^6- one-dimensional chain, a dinuclear[Ag₂(3-bpcd)₃]²⁺ structure unit and two non-coordinated protonated organic ligands 3-bpcd coexists. These structural units are extended into the three-dimensional supramolecular network by the hydrogen bonding interactions. The title complex modified carbon paste electrode displays good electrocatalytic activity toward NO₂^- reduction. Additionally, this complex possesses a remarkable photocatalytic ability for the degradation of Rhodamine B(RhB) dye. CCDC:1401875.
- polyoxometalate,
- compound,
- crystal structure,
- electrocatalytic property,
- photocatalytic activity
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