激活CaO-MgO-SiO<sub>2</sub>长余辉玻璃发光性质

引用本文: 王洪杰, 马腾飞, 张粟, 庞然, 冯婧, 姜丽宏, 李成宇. 激活CaO-MgO-SiO₂长余辉玻璃发光性质[J]. 应用化学, 2016, 33(1): 63-69. doi: 10.11944/j.issn.1000-0518.2016.01.150169 shu

Citation: WANG Hongjie, MA Tengfei, ZHANG Su, PANG Ran, FENG Jing, JIANG Lihong, LI Chengyu. Luminescence Properties of Eu²⁺-activated CaO-MgO-SiO₂ Long-lasting Phosphorescence Glasses[J]. Chinese Journal of Applied Chemistry, 2016, 33(1): 63-69. doi: 10.11944/j.issn.1000-0518.2016.01.150169 shu

激活CaO-MgO-SiO₂长余辉玻璃发光性质

王洪杰 ^a, ,
马腾飞 ^a, ,
张粟 ^{b,
,} ,
庞然 ^b, ,
冯婧 ^b, ,
姜丽宏 ^b, ,
李成宇 ^{b,
,}

1.
a 吉林建筑大学材料科学与工程学院长春 130118;
2.
b 中国科学院长春应用化学研究所, 稀土资源利用国家重点实验室长春 130022

通讯作者: 张粟,副研究员;Tel:0431-85262208;Fax:0431-85262005;E-mail:zhangsu@ciac.ac.cn;研究方向:发光材料;李成宇,研究员;Tel/Fax:0431-85262005;E-mail:cyli@ciac.ac.cn;研究方向:稀土材料; 张粟,副研究员;Tel:0431-85262208;Fax:0431-85262005;E-mail:zhangsu@ciac.ac.cn;研究方向:发光材料;李成宇,研究员;Tel/Fax:0431-85262005;E-mail:cyli@ciac.ac.cn;研究方向:稀土材料

基金项目:
国家自然科学基金资助项目（51102229，51402288，21401184）；吉林省科技发展计划“双十工程”重大科技攻关项目（20140201007GX）；吉林省教育厅“十二五”科学技术研究项目（吉教科合字2014第226号）

摘要: 报道了一种新型的Eu²⁺离子激活硅酸盐玻璃，该玻璃组成为2CaO-MgO-3SiO₂-0.015Eu₂O₃（CMSE）。通过透射光谱、稳态荧光光谱、余辉光谱和热释光等技术手段对CMSE的发光性质进行了深入研究。研究发现CMSE可以被紫光和近紫外光激发，获得黄色长余辉发光。热释光曲线的分析表明，CMSE的长余辉性质主要来自于玻璃基质中陷阱深度为0.83 eV左右的定域能级。研究认为对CMSE发光性质的研究有利于开发新型稀土离子激活近紫外激发LED用硅酸盐玻璃发光材料。

关键词:

Eu²⁺
/ 长余辉
/ 玻璃
/ 发光

English

Luminescence Properties of Eu²⁺-activated CaO-MgO-SiO₂ Long-lasting Phosphorescence Glasses

WANG Hongjie ^a, ,
MA Tengfei ^a, ,
ZHANG Su ^{b,
,} ,
PANG Ran ^b, ,
FENG Jing ^b, ,
JIANG Lihong ^b, ,
LI Chengyu ^{b,
,}

1.
a School of Materials Science and Engineering, Jilin Jianzhu University, Changchun, China 130118;
2.
b State Key Laboratory of Rare Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Corresponding author: 张粟,副研究员;Tel:0431-85262208;Fax:0431-85262005;E-mail:zhangsu@ciac.ac.cn;研究方向:发光材料;李成宇,研究员;Tel/Fax:0431-85262005;E-mail:cyli@ciac.ac.cn;研究方向:稀土材料; 张粟,副研究员;Tel:0431-85262208;Fax:0431-85262005;E-mail:zhangsu@ciac.ac.cn;研究方向:发光材料;李成宇,研究员;Tel/Fax:0431-85262005;E-mail:cyli@ciac.ac.cn;研究方向:稀土材料

Received Date: 14 May 2015
Fund Project:
国家自然科学基金资助项目（51102229，51402288，21401184）；吉林省科技发展计划“双十工程”重大科技攻关项目（20140201007GX）；吉林省教育厅“十二五”科学技术研究项目（吉教科合字2014第226号）

Abstract: In this article, a new Eu²⁺ ion activated silicate glass was prepared. The glass composition is 2CaO-MgO-3SiO₂-0.015Eu₂O₃(CMSE). The transmitted spectrum, steady-state photoluminescence(PL) spectrum, long-lasting phosphorescence(LLP) and thermal glow were performed to investigate the luminescent properties of the CMSE sample. It was found that the CMSE sample can be excited by ultraviolet(UV) and near UV light to give yellow PL emission and LLP. The emission origins from the d-f transition of Eu²⁺. The results of thermal glow curve indicate that the LLP is originated from the trap level with depth of 0.83 eV in the forbidden band of glass host. This study is beneficial for finding other rare earth ions activated luminescent glasses for white light LEDs.

Key words:

1. [1] ZHANG Yao.Synthesis and Luminescence Properties of Phosphors for Alternating Current Driven White Light-Emitting Diode[D].Hefei:Hefei University of Technology,2013(in Chinese).张耀.应用于交流驱动白光LED荧光材料合成及发光特性研究[D].合肥:合肥工业大学,2013.[1] ZHANG Yao.Synthesis and Luminescence Properties of Phosphors for Alternating Current Driven White Light-Emitting Diode[D].Hefei:Hefei University of Technology,2013(in Chinese).张耀.应用于交流驱动白光LED荧光材料合成及发光特性研究[D].合肥:合肥工业大学,2013.
2. [2] SHENG Li.A New AC LED Lighting Equipment Successfully Developed[N].Sci Tech Daily,2013-6-5(in Chinese).盛利.一种新型交流LED照明设备研制成功[N].科技日报,2013-6-5.[2] SHENG Li.A New AC LED Lighting Equipment Successfully Developed[N].Sci Tech Daily,2013-6-5(in Chinese).盛利.一种新型交流LED照明设备研制成功[N].科技日报,2013-6-5.
3. [3] LANG Tianchun,HAN Tao,PENG Lingling,et al.Advance of Phosphors for Near-ultraviolet Light Emitting Diodes[J].Mater Rev,2013,27(23):53-56,65(in Chinese).郎天春,韩涛,彭玲玲,等.近紫外LED用荧光粉的研究进展[J].材料导报,2013,27(23):53-56,65.[3] LANG Tianchun,HAN Tao,PENG Lingling,et al.Advance of Phosphors for Near-ultraviolet Light Emitting Diodes[J].Mater Rev,2013,27(23):53-56,65(in Chinese).郎天春,韩涛,彭玲玲,等.近紫外LED用荧光粉的研究进展[J].材料导报,2013,27(23):53-56,65.
4. [4] ZHU ligang.Preparation and Properties of Rare Earth Ions Doped Luminescence Glasses[D].Changsha:Central South University,2012(in Chinese).朱立刚.稀土离子掺杂发光玻璃的制备与性能研究[D].长沙:中南大学,2012.[4] ZHU ligang.Preparation and Properties of Rare Earth Ions Doped Luminescence Glasses[D].Changsha:Central South University,2012(in Chinese).朱立刚.稀土离子掺杂发光玻璃的制备与性能研究[D].长沙:中南大学,2012.
5. [5] JIANG Limei,ZOU Xiangyu,WEI Qinlei,et al.Preparation and Properties of Fluorine Containing CaO-P₂O₅-SiO₂-Na₂O-B₂O₃ Glass-ceramics[J].Chinese J Appl Chem,2015,32(4):442-446(in Chinese).江莉梅,邹翔宇,韦钦磊,等.含氟CaO-P₂O₅-SiO₂-Na₂O-B₂O₃玻璃陶瓷的制备及性能表征[J].应用化学,2015,32(4):442-446.[5] JIANG Limei,ZOU Xiangyu,WEI Qinlei,et al.Preparation and Properties of Fluorine Containing CaO-P₂O₅-SiO₂-Na₂O-B₂O₃ Glass-ceramics[J].Chinese J Appl Chem,2015,32(4):442-446(in Chinese).江莉梅,邹翔宇,韦钦磊,等.含氟CaO-P₂O₅-SiO₂-Na₂O-B₂O₃玻璃陶瓷的制备及性能表征[J].应用化学,2015,32(4):442-446.
6. [6] JIN Lei,LEI Xiaohua,REN Linjiao,et al.Effect of Critical Process Parameters on Luminescence Properties of Eu²⁺/Dy³⁺ Co-Doped High Silica Luminescence Glass[J].Spectrosc Spectr Anal,2014,34(1):34-38(in Chinese).金雷,雷小华,任林娇,等.Eu²⁺/Dy³⁺共掺高硅氧发光玻璃发光性质的影响因素分析[J].光谱学与光谱分析,2014,34(1):34-38.[6] JIN Lei,LEI Xiaohua,REN Linjiao,et al.Effect of Critical Process Parameters on Luminescence Properties of Eu²⁺/Dy³⁺ Co-Doped High Silica Luminescence Glass[J].Spectrosc Spectr Anal,2014,34(1):34-38(in Chinese).金雷,雷小华,任林娇,等.Eu²⁺/Dy³⁺共掺高硅氧发光玻璃发光性质的影响因素分析[J].光谱学与光谱分析,2014,34(1):34-38.
7. [7] ZHANG Hongbo,WANG Yimin,JIANG Jing,et al.Preparation and Characterization of Neodymium-Doped Phosphate Glass-Ceramic[J].Chinese J Appl Chem,2009,26(8):948-951(in Chinese).张洪波,王轶敏,姜静,等.钕掺杂磷酸盐玻璃陶瓷的制备及表征[J].应用化学,2009,26(8):948-951.[7] ZHANG Hongbo,WANG Yimin,JIANG Jing,et al.Preparation and Characterization of Neodymium-Doped Phosphate Glass-Ceramic[J].Chinese J Appl Chem,2009,26(8):948-951(in Chinese).张洪波,王轶敏,姜静,等.钕掺杂磷酸盐玻璃陶瓷的制备及表征[J].应用化学,2009,26(8):948-951.
8. [8] FENG Yuying,GU Xiaotian,ZHOU Jiahong,et al.Photoluminescence Properties of Silica Glass Doped with Germanium[J].Chinese J Appl Chem,2005,22(8):926-928(in Chinese).冯玉英,顾晓天,周家宏,等.掺锗SiO₂玻璃的发光现象[J].应用化学,2005,22(8):926-928.[8] FENG Yuying,GU Xiaotian,ZHOU Jiahong,et al.Photoluminescence Properties of Silica Glass Doped with Germanium[J].Chinese J Appl Chem,2005,22(8):926-928(in Chinese).冯玉英,顾晓天,周家宏,等.掺锗SiO₂玻璃的发光现象[J].应用化学,2005,22(8):926-928.
9. [9] JIANG Qingyun,LI Chenxia,YE Renguang,et al.Optical Properties of Ce³⁺,Tb³⁺ Co-doped BaYF₅ Glass Ceramics[J].Chinese J Lumin,2011,32(10):1030-1035(in Chinese).江青云,李晨霞,叶仁广,等.Ce³⁺,Tb³⁺共掺BaYF₅微晶玻璃的光学特性[J].发光学报,2011,32(10):1030-1035.[9] JIANG Qingyun,LI Chenxia,YE Renguang,et al.Optical Properties of Ce³⁺,Tb³⁺ Co-doped BaYF₅ Glass Ceramics[J].Chinese J Lumin,2011,32(10):1030-1035(in Chinese).江青云,李晨霞,叶仁广,等.Ce³⁺,Tb³⁺共掺BaYF₅微晶玻璃的光学特性[J].发光学报,2011,32(10):1030-1035.
10. [10] Hussain N S,Reddy Y P,Buddhudu S.Luminescence Spectra of Eu³⁺-doped GeO₂-PbO-Bi₂O₃ Glasses[J].Mater Res Bull,2001,36(10):1813-1821.[10] Hussain N S,Reddy Y P,Buddhudu S.Luminescence Spectra of Eu³⁺-doped GeO₂-PbO-Bi₂O₃ Glasses[J].Mater Res Bull,2001,36(10):1813-1821.
11. [11] Lin Y,Tang Z,Zhang Z,et al.Preparation and Properties of Photoluminescent Rare Earth Doped SrO-MgO-B₂O₃-SiO₂ Glass[J].Mater Sci Engine:B,2001,86(1):79-82.[11] Lin Y,Tang Z,Zhang Z,et al.Preparation and Properties of Photoluminescent Rare Earth Doped SrO-MgO-B₂O₃-SiO₂ Glass[J].Mater Sci Engine:B,2001,86(1):79-82.
12. [12] Yamazaki M,Yamamoto Y,Nagahama S,et al.Long Luminescent Glass:Tb³⁺-activated ZnO-B₂O-SiO₂ Glass[J].J Non-Crystalline Solids,1998,241(1):71-73.[12] Yamazaki M,Yamamoto Y,Nagahama S,et al.Long Luminescent Glass:Tb³⁺-activated ZnO-B₂O-SiO₂ Glass[J].J Non-Crystalline Solids,1998,241(1):71-73.
13. [13] Zhang S,Li C,Su Q.Long Lasting Phosphorescence of Eu²⁺-activated MO-B₂O₃ Glasses[J].Chinese Opt Lett,2011,9(7):071602-071602.[13] Zhang S,Li C,Su Q.Long Lasting Phosphorescence of Eu²⁺-activated MO-B₂O₃ Glasses[J].Chinese Opt Lett,2011,9(7):071602-071602.
14. [14] Zhang Q H,Wang J,Yeh C W,et al.Structure,Composition,Morphology,Photoluminescence and Cathodoluminescence Properties of ZnGeN₂ and ZnGeN₂:Mn²⁺ for Field Emission Displays[J].Acta Mater,2010,58(20):6728-6735.[14] Zhang Q H,Wang J,Yeh C W,et al.Structure,Composition,Morphology,Photoluminescence and Cathodoluminescence Properties of ZnGeN₂ and ZnGeN₂:Mn²⁺ for Field Emission Displays[J].Acta Mater,2010,58(20):6728-6735.
15. [15] Wen H,Tanner P A.Optical Properties of 3d Transition Metal Ion-Doped Sodium Borosilicate Glass[J].J Alloys Compd,2015,625(0):328-335.[15] Wen H,Tanner P A.Optical Properties of 3d Transition Metal Ion-Doped Sodium Borosilicate Glass[J].J Alloys Compd,2015,625(0):328-335.
16. [16] Wang Y,Zhang J,Hou D,et al.Luminescence of Ce³⁺ Activated NaCaPO₄ Under VUV-UV and X-ray Excitation[J].Opt Mater,2012,34(7):1214-1218.[16] Wang Y,Zhang J,Hou D,et al.Luminescence of Ce³⁺ Activated NaCaPO₄ Under VUV-UV and X-ray Excitation[J].Opt Mater,2012,34(7):1214-1218.
17. [17] Ohko Y,Tatsuma T,Fujii T,et al.Multicolour Photochromism of TiO₂ films Loaded with Silver Nanoparticles[J].Nat Mater,2003,2(1):29-31.[17] Ohko Y,Tatsuma T,Fujii T,et al.Multicolour Photochromism of TiO₂ films Loaded with Silver Nanoparticles[J].Nat Mater,2003,2(1):29-31.
18. [18] Zhang X,Wang S,Liu M,et al.Size Tunable Fluorescent Nano-graphite Oxides:Preparation and Cell Imaging Applications[J].Phys Chem Chem Phys,2013,15(43):19013-19018.[18] Zhang X,Wang S,Liu M,et al.Size Tunable Fluorescent Nano-graphite Oxides:Preparation and Cell Imaging Applications[J].Phys Chem Chem Phys,2013,15(43):19013-19018.
19. [19] Liu M,Zhang X,Yang B,et al.Fluorescent Nanoparticles from Starch:Facile Preparation,Tunable Luminescence and Bioimaging[J].Carbohydr Polym,2015,121:49-55.[19] Liu M,Zhang X,Yang B,et al.Fluorescent Nanoparticles from Starch:Facile Preparation,Tunable Luminescence and Bioimaging[J].Carbohydr Polym,2015,121:49-55.
20. [20] Subhan M A,Ahmed T,AwalM R,et al.Synthesis,Structure and Excitation Wavelength Dependent PL Properties of Novel Nanocomposite La₂O₂CO₃·CuO·ZnO[J].Spectrochim Acta Part A:Mol Biomol Spectrosc,2014,132:550-554.[20] Subhan M A,Ahmed T,AwalM R,et al.Synthesis,Structure and Excitation Wavelength Dependent PL Properties of Novel Nanocomposite La₂O₂CO₃·CuO·ZnO[J].Spectrochim Acta Part A:Mol Biomol Spectrosc,2014,132:550-554.
21. [21] Zhang S,Li C,Pang R,et al.Energy Transfer and Excitation Wavelength Dependent Long-lasting Phosphorescence in Pr³⁺ Activated Y₃Al₅O₁₂[J].J Lumin,2011,131(12):2730-2734.[21] Zhang S,Li C,Pang R,et al.Energy Transfer and Excitation Wavelength Dependent Long-lasting Phosphorescence in Pr³⁺ Activated Y₃Al₅O₁₂[J].J Lumin,2011,131(12):2730-2734.
22. [22] Trojan-Piegza J,Niittykoski J,Holsa J,et al.Thermoluminescence and Kinetics of Persistent Luminescence of Vacuum-Sintered Tb³⁺-Doped and Tb³⁺,Ca²⁺-Codoped Lu₂O₃ Materials[J].Chem Mater,2008,20(6):2252-2261.[22] Trojan-Piegza J,Niittykoski J,Holsa J,et al.Thermoluminescence and Kinetics of Persistent Luminescence of Vacuum-Sintered Tb³⁺-Doped and Tb³⁺,Ca²⁺-Codoped Lu₂O₃ Materials[J].Chem Mater,2008,20(6):2252-2261.
23. [23] McKeever,S W S.On the Analysis of Complex Thermoluminescence.Glow-curves:Resolution into Individual Peaks[J].Phys Status Solidi (A),1980,62(1):331-340.[23] McKeever,S W S.On the Analysis of Complex Thermoluminescence.Glow-curves:Resolution into Individual Peaks[J].Phys Status Solidi (A),1980,62(1):331-340.
24. [24] Van den Eeckhout K,Smet P F,Poelman D.Persistent Luminescence in Eu²⁺-Doped Compounds:A Review[J].Materials,2010,3(4):2536-2566.[24] Van den Eeckhout K,Smet P F,Poelman D.Persistent Luminescence in Eu²⁺-Doped Compounds:A Review[J].Materials,2010,3(4):2536-2566.
25. [25] Lecointre A,Ait Benhamou R,Bessi re A,et al.Red Long-lasting Phosphorescence (LLP) in β-TCP Type Ca_9.5Mn (PO₄)₇ Compounds[J].Opt Mater,2011,34(2):376-380.[25] Lecointre A,Ait Benhamou R,Bessi re A,et al.Red Long-lasting Phosphorescence (LLP) in β-TCP Type Ca_9.5Mn (PO₄)₇ Compounds[J].Opt Mater,2011,34(2):376-380.
26. [26] Pang R,Li C,Zhang S,et al.Luminescent Properties of a New Blue Long-lasting Phosphor Ca₂P₂O₇:Eu²⁺,Y³⁺[J].Mater Chem Phys,2009,113(1):215-218.[26] Pang R,Li C,Zhang S,et al.Luminescent Properties of a New Blue Long-lasting Phosphor Ca₂P₂O₇:Eu²⁺,Y³⁺[J].Mater Chem Phys,2009,113(1):215-218.
27. [27] Pang R,Li C,Shi L,et al.A Novel Blue-emitting Long-lasting Pyrophosphate Phosphor Sr₂P₂O₇:Eu²⁺,Y³⁺[J].J Phys Chem Solids,2009,70(2):303-306.[27] Pang R,Li C,Shi L,et al.A Novel Blue-emitting Long-lasting Pyrophosphate Phosphor Sr₂P₂O₇:Eu²⁺,Y³⁺[J].J Phys Chem Solids,2009,70(2):303-306.

扫一扫看文章

计量

PDF下载量: 0
文章访问数: 715
HTML全文浏览量: 98

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

激活CaO-MgO-SiO₂长余辉玻璃发光性质

English

Luminescence Properties of Eu²⁺-activated CaO-MgO-SiO₂ Long-lasting Phosphorescence Glasses

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

激活CaO-MgO-SiO2长余辉玻璃发光性质

English

Luminescence Properties of Eu2+-activated CaO-MgO-SiO2 Long-lasting Phosphorescence Glasses

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

激活CaO-MgO-SiO₂长余辉玻璃发光性质

Luminescence Properties of Eu²⁺-activated CaO-MgO-SiO₂ Long-lasting Phosphorescence Glasses

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs