Citation: ZHANG Dandan, ZHA Xianyu, GAO Baojiao. Synthesizing and Bonding Bidentate Schiff Base Ligand on Side Chain of Polysulfone and Preliminary Exploration of Luminescence Property of Functionalized Polysulfone-Tb(Ⅲ) Complexes[J]. Chinese Journal of Applied Chemistry, ;2016, 33(1): 53-62. doi: 10.11944/j.issn.1000-0518.2016.01.150162 shu

Synthesizing and Bonding Bidentate Schiff Base Ligand on Side Chain of Polysulfone and Preliminary Exploration of Luminescence Property of Functionalized Polysulfone-Tb(Ⅲ) Complexes

1.
Department of Chemical Engineering, North University of China, Taiyuan 030051, China

Corresponding author: GAO Baojiao,
Received Date: 11 May 2015
Available Online: 8 October 2015
Fund Project:

The esterification of chloromethylated polysulfone(CMPSF) with glyoxylic acid(GA) afforded aldehyde(AL) modified PSF-AL. Subsequent condensation of PSF-AL with 3-aminopyridine led to bidentate Schiff base ligand-functionalized PSF-AA. The chemical structure of PSF-AA was characterized by FTIR and ¹H NMR spectra. The binary polymer-rare earth complexes of PSF-(AA)₃-Tb(Ⅲ) and PSF-(AA)₃-Eu(Ⅲ) were prepared and their photoluminescence properties were preliminarily explored. Optimized esterification between CMPSF and GA were performed in N,N-dimethylacetamide at 75℃. The macromolecular PSF-AA does not exhibit sensitization towards Eu(Ⅲ) ion, whereas PSF-AA can strongly sensitize the fluorescence emission of Tb(Ⅲ) ion. The complex PSF-(AA)₃-Tb(Ⅲ) emits characteristic green fluorescence of Tb(Ⅲ) ion.
- polysulfone,
- polymer-rare earth complex,
- bidentate schiff base ligand,
- sensitization,
- Tb(Ⅲ) ion
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