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Citation: SHI Yufang, SUN Jinyu, LIU Chengqi, ZHAO Minggen. Synthesis and Nonlinear Optical Properties of 1-Ferrocenyl-3-((9-ethyl) carbazole-3-yl) acrylic Ketone[J]. Chinese Journal of Applied Chemistry, ;2015, 32(9): 994-998. doi: 10.11944/j.issn.1000-0518.2015.09.150020 shu

Synthesis and Nonlinear Optical Properties of 1-Ferrocenyl-3-((9-ethyl) carbazole-3-yl) acrylic Ketone

1.
Department of Chemistry, Xinzhou Teachers University, Xinzhou, Shanxi 034000, China

Corresponding author: ZHAO Minggen,
Received Date: 19 January 2015
Available Online: 7 May 2015
Fund Project: 山西省教育厅科技开发项目(20121022) (20121022)忻州师范学院重点学科专项课题(XK201205) (XK201205)

A new nonlinear optical (NLO) organic material,1-ferrocenyl-3-((9-ethyl) carbazole-3-yl) acrylic ketone (FCAK),was synthesized and characterized by IR,MS,NMR and element analysis.The title compound exhibits third-order nonlinear optical properties.The related parameters were obtained by powder technique using the Nd:YAG laser.When the laser pulse is four nanoseconds,the nonlinear refractive index n₂ is-3.5×10^-18 m²/W,the nonlinear absorption coefficient β is -2.7×10^-11 m/W,the third-order nonlinear polarizability χ⁽³⁾ is 2.04×10^-12 esu,the third-order nonlinear molecular hyperpolarizability γ is 1.1×10^-30 esu.When the laser pulse is twenty one picoseconds,n₂ is 0.55×10^-18 m²/W,β is -0.6×10^-11 m/W,χ⁽³⁾ is 3.4×10^-13 esu,γ is 0.13×10^-30 esu.
- ferrocenyl derivative,
- ferrocenyl-((ethyl) carbazole-yl) acrylic ketone,
- Chalcone,
- synthesis,
- nonlinear optical property
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