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Citation: ZHANG Chenglu, SUN Lijie, SONG Buer, GUO Yang, ZHAO Baocheng, TANG Jie, XI Huan. Synthesis and Application of Novel Tripod-type Benzimidazolium Compounds[J]. Chinese Journal of Applied Chemistry, ;2015, 32(8): 873-883. doi: 10.11944/j.issn.1000-0518.2015.08.140402 shu

Synthesis and Application of Novel Tripod-type Benzimidazolium Compounds

1.
College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, China

Corresponding author: ZHANG Chenglu,
Received Date: 19 November 2014
Available Online: 14 April 2015
Fund Project: 辽宁省教育厅科学技术项目(2009A426)资助 (2009A426)

Fifteen new tripod type benzimidazolium salts (3a~3o) were synthesized and characterized by IR,NMR and HRMS.The plant growth regulating activities of compound 3 were evaluated.Compounds 3a,3c,3f,3g,3h,3i and 3j exhibit excellent cytokinesis activities up to 88.3% at the concentration of 10 mg/L which are higher than that of the reference triadimefon (50.2%),but their auxin activities are not obviously effective.Nearly all the target compounds have excellent herbicidal activity,while compound 3i is the best with 95.6%.The fluorescent identification of the four representative target molecules on six important anions was explored by fluorescence spectrum.The target compounds can be used as fluorescence probe for I^- identification.
- benzimidazole,
- biological activity,
- plant growth regulator,
- anionic identification
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