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Citation: CHU Chaosen, WANG Xiaoli, HU Yutao, YAN Xiumei, WANG Zheng. Catalyzed Oxidation of Alcohols by 2, 2, 6, 6-Tetramethyl-1-iperidinyloxy with Sodium Bromate and Ferric Chloride as Accelorators[J]. Chinese Journal of Applied Chemistry, ;2015, 32(6): 666-670. doi: 10.11944/j.issn.1000-0518.2015.06.140331 shu

Catalyzed Oxidation of Alcohols by 2, 2, 6, 6-Tetramethyl-1-iperidinyloxy with Sodium Bromate and Ferric Chloride as Accelorators

CHU Chaosen ^a,b,, ,
WANG Xiaoli ^a ,
HU Yutao ^a ,
YAN Xiumei ^c ,
WANG Zheng ^c

1.
a Lianyungang TCM Branch of Jiangsu Union Technical Institute, Lianyungang, Jiangsu 222047, China;
2.
b Ltanyungang Common Technological Center for Drug Research and Development, Lianyungang, Jiangsu 222047, China;
3.
c Jiangsu Deyuan Pharmaceutical Co., Ltd., Lianyungang, Jiangsu 222047, China

Corresponding author: CHU Chaosen,
Received Date: 24 September 2014
Available Online: 31 December 2014
Fund Project: 江苏省"青蓝工程"培养基金(2014) (2014)连云港市药物研发共性技术中心科技项目(2013-2015) (2013-2015)江苏省高水平示范性实训基地建设项目专项经费资助(2013-2014) (2013-2014)

A 2,2,6,6-tetramethyl-1-piperidinyloxy catalytic system with sodium bromate and ferric chloride as accelorators(NaBrO₃-FeCl₃-TEMPO) was developed for efficient oxidation of alcohols. Taking example for benzyl alcohol,the molar ratios of TEMPO,NaBrO₃,H₂SO₄,FeCl₃·6H₂O relative to the substrate are optimized at 2%,35%,3.7% and 2%,respectively. Aromatic alcohol,aliphatic alcohol and heterocyclic alcohol can be effectively oxidized to the corresponding carbonyl compounds with high yields up to 99% and selectivity up to 99% at room temperature even under anaerobic conditions.
- tetramethyl-piperidinyloxy,
- sodium bromate,
- alcohol,
- oxidation
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