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Citation: XU Qijie, SHI Wenzhong, ZUO Chunshan, LIU Dayong, YANG Chun, ZHAO Xiang, LIU Pengcheng. Catalytic Properties of Carbon Supported Pd/Ce Bimetallic Catalyst on Heck Reaction[J]. Chinese Journal of Applied Chemistry, ;2015, 32(4): 428-432. doi: 10.11944/j.issn.1000-0518.2015.04.140298 shu

Catalytic Properties of Carbon Supported Pd/Ce Bimetallic Catalyst on Heck Reaction

1.
Department of Chemistry & Chemical Engineering, Huanghuai University, Zhumadian, He'nan 463000, China

Corresponding author: SHI Wenzhong,
Received Date: 27 August 2014
Available Online: 17 December 2014
Fund Project: 河南省自然科学基金项目(0624270040,092300410121,112300410184) (0624270040,092300410121,112300410184)

Carbon supported Pd/Ce bimetallic catalyst was prepared readily for Heck reaction. The effect of reaction conditions on the catalytic properties of carbon supported Pd/Ce bimetallic catalyst was studied in details with the model Heck reaction of iodobenzene and acrylic acid. The results show that carbon supported Pd/Ce bimetallic catalyst can effectively catalyze the Heck reactions under the conditions of 130℃,5 h,DMF as the solvent,and Bu₃ N as the base to afford the product with a yield of over 70%. Additionally,the heterogeneous carbon supported Pd/Ce bimetallic catalyst can be easily separated from the reaction solution.Furthermore,the catalyst can be reused for 3 times with a yield of 69% and without the significant loss of catalytic efficiency.
- Heck reaction,
- bimetallic catalyst,
- catalytic
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