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Citation: TAN Yuhui, WANG Yan, ZHANG Meng, GAO Jixing, XU Qing, TANG Yunzhi, YANG Shaoping. Electrodeposited Zn-Ni-P-La Alloys Coating for Electrolytic Copper Foil[J]. Chinese Journal of Applied Chemistry, ;2015, 32(4): 458-463. doi: 10.11944/j.issn.1000-0518.2015.04.140266 shu

Electrodeposited Zn-Ni-P-La Alloys Coating for Electrolytic Copper Foil

TAN Yuhui ^a ,
WANG Yan ^a ,
ZHANG Meng ^a ,
GAO Jixing ^a ,
XU Qing ^a ,
TANG Yunzhi ^a,, ,
YANG Shaoping ^b,,

1.
a School of Materials and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China;
2.
b School of Mechanical & Material Engineering, Wuzhou University, Wuzhou, Guangxi 543002, China

Corresponding author: TANG Yunzhi, YANG Shaoping,
Received Date: 28 July 2014
Available Online: 5 November 2014
Fund Project: 国家自然科学基金(21261009,21461010,21471070) (21261009,21461010,21471070)江西省科技厅科技支撑计划(20133BBE50020) (20133BBE50020)江西省教育厅项目(GJJ13434)资助 (GJJ13434)

In order to alleviate the situation of the country' s reliance on importing high-performance copper foil,the experiment was carried out by introducing metalloid(P) and rare earth(La) in the Zn-Ni alloy coating to obtain high corrosion resistance for the copper foil. The quality of the copper foil coating was characterized by the X-ray photoelectron spectrscopy(XPS),powder X-ray diffraction(XRD) and scanning electron microscope(SEM). Zn-Ni-P-La amorphous alloy coating with well-distributed and dense crystallization was achieved by optimizing the experimental process parameters. The unpassivated copper foil can keep color for one hour in a 180 degree oven and exhibits good antioxidation and anticorrosion abilities. It indicates that a proper amount of P and La in the coating plays an important role in improving the quality of the copper foil coating,which has a good industrial application prospect.
- electrolytic copper foil,
- alloy electrodeposition,
- rare earth additive,
- amorphous
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