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Citation: HAN Lin, LIU Xiaojuan, MENG Junling, YAO Chuan'gang, WU Xiaojie, MENG Jiana. Structure Refinements and Magnetic Properties of LaPbMnSbO₆[J]. Chinese Journal of Applied Chemistry, ;2015, 32(3): 350-355. doi: 10.11944/j.issn.1000-0518.2015.03.140159 shu

Structure Refinements and Magnetic Properties of LaPbMnSbO₆

HAN Lin ^a,b ,
LIU Xiaojuan ^a ,
MENG Junling ^a,b ,
YAO Chuan'gang ^a,b ,
WU Xiaojie ^a ,
MENG Jiana ^a,,

1.
a State Key Laboratory of Rare Earth Resources Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
2.
b University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: MENG Jiana,
Received Date: 5 May 2014
Available Online: 5 November 2014
Fund Project: 国家自然科学基金(21221061,21071141,51372244) (21221061,21071141,51372244)吉林省自然科学基金(201115126)资助项目 (201115126)

Double perovskite LaPbMnSbO₆ was synthesized by two-step semi-chemical method,and the crystal structure and magnetic properties have been investigated. The crystal structure has been solved by X-ray diffraction(XRD) data in the monoclinic space group P₁/n(No. 14). The Mn₆ and SbO₆ octahedra are rock-salt ordered over the B-site of the perovskite structure. Due to the existence of Pb²⁺ ions,secondorder Jahn-Teller effect is occurred and the lattice distortions are anisotropic in the interior of BO₆ octahedra.The magnetization curves show a typical antiferromagnetic ordering, with an antiferromagnetic ordering transition temperature at T_N=9 K.
- double perovskites,
- two-step semi-chemical,
- structure refinements,
- magnetic properties
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Structure Refinements and Magnetic Properties of LaPbMnSbO₆