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Citation: XU Bailu, QU Xiaogang. Effect of Nucleobase Linkers on Morphologies and Adsorption Properties of Metal-biomolecule Frameworks(MBioFs)[J]. Chinese Journal of Applied Chemistry, ;2015, 32(1): 27-33. doi: 10.11944/j.issn.1000-0518.2015.01.140329 shu

Effect of Nucleobase Linkers on Morphologies and Adsorption Properties of Metal-biomolecule Frameworks(MBioFs)

XU Bailu ^a,b ,
QU Xiaogang ^a,,

1.
a Laboratory of Chemical Biology, State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
2.
b University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: QU Xiaogang,
Received Date: 23 September 2014
Available Online: 29 October 2014
Fund Project: 973工程(2011CB936004) (2011CB936004)国家自然科学基金(21210002)资助项目 (21210002)

Metal-biomolecule frameworks (MBioFs) are a recently-identified class of porous polymeric materials,consisting of metal ions linked together by biomolecules as organic bridging ligands,and are emerging as a new interdiscipline based on molecular coordination chemistry and biomaterials science. Nucleobases,the key constituents of nucleic acids,have accessible nitrogen and oxygen electron lone pairs, which allows these molecules to act as multidentate organic ligands. In this paper,a series of metalbiomolecule frameworks was successfully synthesized with different nucleobases via a solvothermal system. These MBioFs exhibit brilliant micro-structures which are distinct with each other and dependent on the nucleobase linkers consisting in the frameworks for their different coordination properties. In addition,they are able to adsorb and release organic molecules repeatedly,and can be regarded as the sorbent to treat waste water.
- metal-biomolecule frameworks,
- nucleobase,
- porous polymeric material,
- adsorption properties
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