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Citation: QIN Yanfang, QI Yong, HUANG Yuejun, HOU Yingjie, AN Yu, ZHANG Dengke, HAN Yunke, PAN Jigang. Microwave-assisted Synthesis of Cu(Ⅱ) meso-Tetra (Schiff-base substituted phenyl) porphyrins[J]. Chinese Journal of Applied Chemistry, ;2015, 32(1): 53-59. doi: 10.11944/j.issn.1000-0518.2015.01.140121 shu

Microwave-assisted Synthesis of Cu(Ⅱ) meso-Tetra (Schiff-base substituted phenyl) porphyrins

QIN Yanfang ^a ,
QI Yong ^a ,
HUANG Yuejun ^b ,
HOU Yingjie ^a ,
AN Yu ^a ,
ZHANG Dengke ^a ,
HAN Yunke ^a ,
PAN Jigang ^a,,

1.
a School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, China;
2.
b Shanxi Pharmaceutical College, Taiyuan 030031, China

Corresponding author: PAN Jigang,
Received Date: 11 April 2014
Available Online: 8 July 2014

Cu (Ⅱ) meso-tetra (Schiff-base substituted phenyl) porphyrins were synthesized under microwave heating. The experimental results show that the species of substituents on substituted benzaldehyde affect the condensation reaction rates and yields between benzaldehyde and Cu (Ⅱ) meso-5,10,15,20-tetrakis (4-aminophenyl) porphyrin. Cu complex can be formed between the side-chain of salicylaldehyde-Schiff base copper metalloporphyrin and copper ions in alkaline conditions. The conversion and the selectivity of its catalytic oxidation of cyclohexane to cyclohexanone is up to 7.68% and 60.87%,respevtively.
- Cu(Ⅱ) meso-tetrakis(aminophenyl) porphyrin,
- Cu(Ⅱ) meso-tetra(Schiff-base substituted phenyl) porphyrins,
- microwave,
- Cu complex,
- catalytic oxidation
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