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Citation: XIA Xiaojie, FANG Kuanjun, REN Bin, CAI Yuqing, ZHANG Jianbo, ZHAO Yunguo, HAO Longyun. Colored Poly(styrene-co-acrylic acid) Nanospheres Prepared by Dyeing with Disperse Dyes[J]. Chinese Journal of Applied Chemistry, ;2015, 32(1): 64-70. doi: 10.11944/j.issn.1000-0518.2015.01.140117 shu

Colored Poly(styrene-co-acrylic acid) Nanospheres Prepared by Dyeing with Disperse Dyes

1.
The Growing Base for State Key Laboratory of Fiber Materials and Modern Textiles, Qingdao University, Qingdao, Shandong 266071, China

Corresponding author: FANG Kuanjun,
Received Date: 8 April 2014
Available Online: 26 June 2014
Fund Project: 国家自然科学基金(51173086) (51173086)山东省自主创新成果转化重大专项(2012ZHZX1A0914) (2012ZHZX1A0914)科技部国家科技支撑计划项目(2014BAC13B02,2014BAE01B01)资助 (2014BAC13B02,2014BAE01B01)

Two disperse dyes were used to color poly(styrene-co-acrylic acid)[P(St-co-AA)]nanospheres at temperatures below the glass transition temperature of the nanoshperes (110.69℃). Then we studied the effect of temperature(75~95℃) and dye concentration (1%~5%) on the dye content adsorbed on the nanopheres. The results show that the higher the dyeing temperature the more the dye stained on the nanospheres. Increasing the dye concentration of dyeing bath results in higher dye contents on the nanospheres. Higher dye contents gave brighter and deeper colors of the nanospheres. The dye contents of the nanospheres colored with disperse blue 2BLN,which has two amino groups and two hydroxyl groups,are lower than the dye contents of the nanospheres colored with disperse red FB,which has one amino group and one hydroxyl group. After being dyed,the nanospheres become very rough and the size increases 23 nm. The cotton fabrics after cationic modification were dyed with the colored nanospheres. The dyed cotton fabrics obtain deep and bright colors with a very small amount of the colored nanospheres.
- disperse dye,
- poly(styrene-co-acrylic acid),
- colored nanosphere,
- dye content
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