Citation: LI Zhen, LIU Han-Meng, YAO Zhi-Xia, SUN Yu-Jing, LI Zhuang. Preparation and Characterization of Titanium Dioxide Nanotube Array/Titanium pH Electrode[J]. Chinese Journal of Analytical Chemistry, ;2018, 46(12): 1961-1967. doi: 10.11895/j.issn.0253-3820.181459 shu

Preparation and Characterization of Titanium Dioxide Nanotube Array/Titanium pH Electrode

LI Zhen ^1,2, ,
LIU Han-Meng ^1,3 ,
YAO Zhi-Xia ^1,3 ,
SUN Yu-Jing ^1,2,3 ,
LI Zhuang ^1,2,3

1.
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
2.
University of Chinese Academy of Sciences, Beijing 100049, China;
3.
University of Science and Technology of China, Hefei 230026, China

Received Date: 13 July 2018
Revised Date: 28 September 2018

Fund Project: This work was supported by the National Key Research and Development Program of China (No.2016YFC1400601-2) and the National Natural Science Foundation of China (No. 21405146).

A method for rapidly preparing titanium dioxide nanotube array/titanium (TiO₂NTAs/Ti) as a pH electrode by using anodization method in a mixed solution containing NH₄F and ethylene glycol and water was established. The electrodes were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The possible pH response mechanisms were discussed by the hydrophilicity, specific surface area, and surface chemisorbed oxygen (OH) of the electrodes. Under the optimized conditions including electrolysis voltage of 30 V, a mixed solution containing NH₄F (0.5%, w/w) and ethylene glycol and water (9:1, V/V) as electrolyte and anodization time of 10 min, the prepared TiO₂NTAs/Ti electrode in Beretan-Robson (B-R) buffer solution (pH=3-11) exhibited an excellent pH response with a sensitivity of (-55.17±0.28) mV/pH and a correlation coefficient (R²) of above 0.9966. The results of the ion interference experiments showed that the effect of common ion on the electrode was negligible. The electrode had good stability and was successfully applied to the determination of pH value of vitamin drink and seawater.
- Titanium dioxide,
- Nanotube,
- pH electrode,
- Anodic oxidation,
- Metal oxide
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
1. [1]
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