Citation: LI Jing-Jing, LI Hui, JIA Li-Ping, MA Rong-Na, JIA Wen-Li, WANG Huai-Sheng. Construction of Nonenzymatic Glucose Sensor Based on One Step Preparation of Poly(3, 4-ethylenedioxythiophene) Graphene Composite Materials by Pulse Potentiostatic Method[J]. Chinese Journal of Analytical Chemistry, ;2017, 45(12): 2004-2010. doi: 10.11895/j.issn.0253-3820.171306 shu

Construction of Nonenzymatic Glucose Sensor Based on One Step Preparation of Poly(3, 4-ethylenedioxythiophene) Graphene Composite Materials by Pulse Potentiostatic Method

College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, China

Corresponding author: WANG Huai-Sheng, hswang@lcu.edu.cn
Received Date: 9 October 2017
Accepted Date: 8 November 2017

Fund Project: This work was supported by the National Natural Science Foundation of China (Nos. 21375055, 21427808, 21405070)the National Natural Science Foundation of China 21427808the National Natural Science Foundation of China 21405070the National Natural Science Foundation of China 21375055

Figures(7)

The Poly(3, 4-ethylenedioxythiophene) graphene (PEDOT-rGO) composite film was prepared by one step pulse potentiostatic method, based on the π-π^* interaction and the polymerization reaction of hydrogen bond between the graphene (rGO) and the aromatic ring of 3, 4-ethylenedioxythiophene (EDOT) monomer. Then the nickel nanoparticles (NiNPs) were electrodeposited on composite film to obtain a composite film-modified glassy carbon electrode (NiNPs/PEDOT-rGO/GCE). The catalytic performance of NiNPs/PEDOT-rGO/GCE towards the oxidation of glucose was studied by electrochemical method. The experimental results showed that the NiNPs/PEDOT-rGO/GCE could be used as a nonenzyematic sensor for detection of glucose. This method had high stability, good selectivity, wide linear range (2 μmol/L-58 mmol/L) and low detection limit (0.7 μmol/L), realizing the rapid and sensitive detection of glucose.
- Poly-3, 4-ethylenedioxythiophene,
- Graphene composites,
- Nano-nickel,
- Glucose,
- Nonenzyematic sensor
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