Citation: HE Quan-Guo, LIANG Jing, LI Guang-Li, DENG Pei-Hong, LIU Jun, LIU Xiao-Peng. Electrochemical Detection of Dopamine Based on MnO₂ Nanowires/Reduced Graphene Oxide Composites Modified Glassy Carbon Electrode[J]. Chinese Journal of Analytical Chemistry, ;2018, 46(3): 438-445. doi: 10.11895/j.issn.0253-3820.171183 shu

Electrochemical Detection of Dopamine Based on MnO₂ Nanowires/Reduced Graphene Oxide Composites Modified Glassy Carbon Electrode

1.
College of Life Sciences and Chemistry, Hunan University of Technology, Zhuzhou 412007 China;
2.
Department of Chemistry and Material Science, Hengyang Normal University, Hengyang 421008 China

Received Date: 21 August 2017
Revised Date: 2 January 2018

Fund Project: This work was supported by the National Natural Science Foundation of China (No. 61703152), Natural Science Foundation of Hunan Province, China (No.2016JJ4010), and Hengyang Normal University Provincial Platform Open Fund Project, China (No.GD16K02).

MnO₂ nanowires-reduced graphene oxide composite (MnO₂-RGO) was used to modify glassy carbon electrodes (GCE) and applied for the electrochemical determination of dopamine (DA). The microstructure of MnO₂ nanowires and MnO₂-RGO nanocomposite material was characterized by scanning microscope and X-ray powder diffraction. Then the electrochemical reduction condition for preparing MnO₂-RGO/GCE and experimental conditions for determining DA were optimized systematically. The electrochemical behavior of DA on the bare electrode and RGO or MnO₂-RGO modified electrodes was also investigated in pH 3.5 phosphate buffer solution (PBS) by cyclic voltammetry. The results shows that the oxidation peaks of ascorbic acid (AA), dopamine (DA) and uric acid (UA) can be well separated and the peak to peak separations were 268 mV (AA-DA) and 128 mV (DA-UA), respectively. Moreover, the linear response ranges for the determination of DA were 0.06-1.0 μmol/L and 1.0-80 μmol/L with the detection limit of 1.0 nmol/L (S/N=3). The proposed method has been applied to the determination of dopamine in human blood serum sample with satisfactory results.
- MnO₂ nanowires,
- Reduced graphene oxide,
- Modified electrode,
- Dopamine,
- Electrocatalytic oxidation
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
44. [44]
45. [45]
1. [1]
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2. [2]
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3. [3]
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Electrochemical Detection of Dopamine Based on MnO₂ Nanowires/Reduced Graphene Oxide Composites Modified Glassy Carbon Electrode