Citation:
LI Jing, HAN Shu-Hua. Bifunctional Fluorescence Molecular Probes for Detection of Aluminum(Ⅲ) and pH[J]. Chinese Journal of Analytical Chemistry,
;2017, 45(9): 1346-1352.
doi:
10.11895/j.issn.0253-3820.170125
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A fluorescent molecular probe R6G-Flu was prepared by modifying fluorescein onto Rhodamine 6G. The probe could be used to recognize Al3+ specifically, and the detection limit could reach as low as 10-8 mol/L. After addition of Al3+ (10 μmol/L) to the probe, the solution showed a color change from colorless to pink, and green fluorescence was observed under the UV irradiation, which could be perceived by the naked eye. By measuring the fluorescence emission intensity of R6G-Flu at different pH, the probe could also be used to determine pH in acidic pH range (3.00-6.00) and basic pH range (8.00-10.50). The detection results of Al3+ and pH indicated that the R6G-Flu was a dual-functional fluorescent molecular probe.
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