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Citation: ZHANG Xian-Chen, LI Rong, ZHOU Yan-Ping, BO Yan-Na, WANG Jing-Li, HU Yi-Guang. Simultaneous Determination of Seven Kinds of Fluorescent White Agents in Mushroom by QuEChERS-Ultra Performance Liquid Chromatography-Tandem Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry, ;2017, 45(5): 777-783. doi: 10.11895/j.issn.0253-3820.160866 shu

Simultaneous Determination of Seven Kinds of Fluorescent White Agents in Mushroom by QuEChERS-Ultra Performance Liquid Chromatography-Tandem Mass Spectrometry

1.
Zhongshan Subcenter of Inspection and Quarantine Technology Center, Guangdong Entry-Exit Inspection and Quarantine Bureau, Zhongshan 528403, China;
2.
Key Laboratory of Product Packaging and Logistics, Institute of Packaging Engineering of Guangdong Higher Education Institutes, Jinan University, Zhuhai 519070, China

Received Date: 27 November 2016
Revised Date: 20 March 2017

A method based on QuEChERS coupled with ultra performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS) was developed for the determination of seven kinds of fluorescent white agent residues in mushroom. After mixing with 10 mL of water, the sample was extracted with acidified acetonitrile, cleaned up by C₁₈, primary secondary amine (PSA) and MgSO₄. The separation of seven kinds of fluorescent white agents was performed on a C₁₈ column with a gradient elution of acetonitrile and 0.1% acidified water as mobile phase. The target compounds were detected by electrospray ionization mass spectrometry in positive ion mode with multi reaction monitoring (MRM). Under the optimum conditions, the method had good linear relationship in the determination of the seven kinds of fluorescent white agents in a certain concentration range, with correlation coefficients greater than 0.991. Moreover, the limits of detection (S/N=3) were 0.05-0.4 μg/kg, the limits of quantitation (S/N=10) were 0.2-1.3 μg/kg, and the average recoveries for seven kinds of fluorescent white agent residues in msushroom were 70.1%-109.2%. In comparison with previous methods, the new procedure has characteristics of simple sample preparation and higher sensitivity.
- Ultra performance liquid chromatography-tandem mass spectrometry,
- Fluorescent white agents,
- Mushroom
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

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