Citation: GAO Min-Jun, LIU Gen-Qi, XUE Ya-Feng, CHEN Xiao-Juan, SHI Wei-Jiang, FAN Xiao-Dong. Erythromycin Molecularly Imprinted Two-dimensional Photonic Crystal Hydrogel Sensor[J]. Chinese Journal of Analytical Chemistry, ;2017, 45(5): 727-733. doi: 10.11895/j.issn.0253-3820.160771 shu

Erythromycin Molecularly Imprinted Two-dimensional Photonic Crystal Hydrogel Sensor

Shaanxi Key Laboratory of Macromolecular Science and Technology, Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi'an 710129, China

Received Date: 19 October 2016
Revised Date: 4 February 2017

A molecularly imprinted two-dimensional photonic crystal hydrogel sensor was developed with erythromycin as imprinted molecule, polystyrene two-dimensional photonic crystal as templates, methanol as solvent, methacrylic acid as monomers and ethylene glycol dimethylacrylate as cross-linkers. The imprinted molecule was removed by methanol/acetic acid (9∶1, V/V). The results showed that the diameter of Debye ring increased 6 mm when the concentration of EM changed from 0 to 1×10^-6 mol/L. Namely the lattice spacing decreased 30 nm. In addition, the diameter of Debye ring only increased 1.5 and 2.0 mm when the hydrogel immersed in 1×10^-6 mol/L roxithromycin (RM) or erythromycin ethylsuccinate (EEs) solution. The result indicated that the sensor had high selectivity and could be used in determination of erythromycin with low cost and easy operation.
- Molecularly imprinting,
- Two-dimensional photonic crystal,
- Hydrogel,
- Erythromycin,
- Sensor
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沈阳化工大学材料科学与工程学院沈阳 110142