Citation: SONG Jing, ZHENG Yuan, HUO Chang-Hong, LIU Jian-Fang. Study on Quantitative Structure-Retention Relationships of Microemulsion Electrokinetic Chromatography Using Phospholipids as Surfactant[J]. Chinese Journal of Analytical Chemistry, ;2017, 45(5): 654-661,753. doi: 10.11895/j.issn.0253-3820.160732 shu

Study on Quantitative Structure-Retention Relationships of Microemulsion Electrokinetic Chromatography Using Phospholipids as Surfactant

1.
Department of Graduate School, Hebei Medical University, Shijiazhuang 050017, China;
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Department of Pharmacy, General Hospital of Tianjin Medical University, Tianjin 300052, China;
3.
Department of Pharmacy, Bethune International Peace Hospital, Shijiazhuang 050082, China

Received Date: 28 September 2016
Revised Date: 20 January 2017

Fund Project: This work was supported by the National Natural Science Foundation of China (No. 81202501)

Some new types of microemulsion using phospholipids as the main surfactant were prepared for electrokinetic chromatography and the quantitative structure-retention relationship of neutral solutes in these microemulsion electrokinetic chromatography (MEEKC) systems was studied by solvation parameters model. By using dynamic coating capillary, and with dimethyl sulfoxide (DMSO) and dodecyl benzene as the marker of electroosmotic flow and microemulsion droplets, a total of 17 kinds of stable microemulsions containing soybean phospholipids or other surfactants were prepared and the linear salvation energy relationship equations were developed for these MEEKC systems with 26 small neutral compounds. The coefficients of linear solvation energy relationship (LSER) equations were used to evaluate the similarity of two MEEKC systems. Results indicated that LSER characteristics of phospholipids-MEEKC systems were similar to those of other microemulsion systems. The volume and hydrogen bond basicity of solutes were mostly contributed to the retention in MEEKC. The different types and concentration of oil phase had no evident influence on the retention.
- Microemulsion electrokinetic chromatography,
- Soybean phospholipids,
- Retention indice,
- Linear solvation energy relationship
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沈阳化工大学材料科学与工程学院沈阳 110142