Citation: CUI Shu-Hua, LI Rui-Juan, ZHANG Xiao-Mei, CHENG Gang, WANG Yu, LI Zheng-Yi. Determination of New Bistrifluron, Cyantraniliprole and SYP9080 Residues in Fruits and Vegetables by Liquid Chromatography- Tandem Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry, ;2017, 45(4): 545-552. doi: 10.11895/j.issn.0253-3820.160493 shu

Determination of New Bistrifluron, Cyantraniliprole and SYP9080 Residues in Fruits and Vegetables by Liquid Chromatography- Tandem Mass Spectrometry

1.
Inspection and Quarantine Technology Center of Shandong Exit/Entry Inspection and Quarantine Bureau, Qingdao 266002, China;
2.
Institute of Plant Protection, Shandong Academy of Agriculture, Jinan 250100, China

Received Date: 29 June 2016
Revised Date: 4 January 2017

A liquid chromatography-tandem mass spectrometric (LC-MS/MS) method was developed for the determination of bistrifluron, cyantraniliprole and SYP9080 residues in fruits and vegetables. The analytes were extracted from samples with acetonitrile, and purified by dispersion solid phase extraction using C18 and primary secondary amine (PSA) as solid phase adsorbent, then analyzed by LC-MS/MS. Bistrifluron and SYP9080 were analyzed with negative ion multiple-reaction monitoring (MRM), cyantraniliprole was analyzed with positive ion MRM. The matrix-induced weakening effect was observed in the analysis of cyantraniliprole and SYP9080 in several samples including cucumber, apple and onion, and the weakening extent of the matrix-induced effect depended on the sample properties. But no matrix effect was found in the analysis of bistrifluron in several samples. The interference of matrix was reduced by using the matrix-matched calibration standards curve in the analysis of cyantraniliprole and SYP9080. Bistrifluron could be quantified by an external standard of the matrix-matched calibration standards or the pure solvent calibration standards. The linear range was from 0.2 μg/L to 100 μg/L for bistrifluron, cyantraniliprole and SYP9080 with the good correlation coefficients (r≥0.9990). The recoveries of cucumber, grape, apple and scallion added bistrifluron at 0.005-2 mg/kg were 79.8%-99.9%, with relative standard deviations (RSD) of 3.6%-9.8%. The limits of quantification (S/N=10) were 0.210 μg/kg, 0.160 μg/kg and 0.004 μg/kg, and limits of detection (S/N=3) were 0.064 μg/kg, 0.048 μg/kg and 0.001 μg/kg for bistrifluron, cyantraniliprole and SYP9080, respectively.
- Liquid chromatography-tandem mass spectrometry,
- Fruits and vegetables,
- Residues,
- Bistrifluron,
- SYP9080
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沈阳化工大学材料科学与工程学院沈阳 110142