Citation: XU Hua-Lei, LING Xing, ZHANG Xiao-Hua, JIANG Tao, ZHU Zhi-Qiang, QIU Chun-Ling, TIAN Di. Development of Microwave Plasma Torch Mass Quadrupole Spectrometer[J]. Chinese Journal of Analytical Chemistry, ;2015, 43(12): 1955-1961. doi: 10.11895/j.issn.0253-3820.150520 shu

Development of Microwave Plasma Torch Mass Quadrupole Spectrometer

1.
¹ College of Instrument Science & Electrical Engineering, Jilin University, Changchun 130000, China;

Corresponding author: TIAN Di,
Received Date: 25 June 2015
Available Online: 24 August 2015
Fund Project: 本文系国家重大科学仪器设备开发专项(Nos.2011YQ1401500402,2011YQ14015009)资助 (Nos.2011YQ1401500402,2011YQ14015009)

A novel quadrupole mass spectrometer using microwave plasma torch as the ionization source was developed(MPT-QMS) for the analysis of trace metal elements in water samples. The influence of ion funnel on instrument performance and analytical outputs was studied and illustrated. The results showed that it could lead to effective collision induced dissociation(CID) by modulating the RF voltage of the ion funnel, which quantitatively broke polyatomic ions produced by MPT into mono-atomic ions. Such effect significantly reduced the complexity of the mass spectrum caused by multi-atom ions. In contrast to a linear ion trap mass spectrometer(LTQ) without ion funnel, the result of MPT-QMS was easier to be identified. A mixed sample containing 20 metal elements was detected by this instrument, the detection limits of most elements were between 0.02 and 1.4 ng/mL. Compared to ICP-MS, MPT-QMS was only 10% of power and gas consumption, and was suitable for the analysis of water samples when carried by a vehicle.
- Microwave plasma torch,
- Quadrupole mass spectrometer,
- Metal detection,
- Ion funnel,
- Collision induced dissociation
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