Citation: Yingtong FAN, Yujin YAO, Shouhao WAN, Yihang SHEN, Xiang GAO, Cuie ZHAO. Construction of copper tetrakis(4-carboxyphenyl)porphyrin/silver nanowire composite electrode for flexible and transparent supercapacitors[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(7): 1309-1317. doi: 10.11862/CJIC.20250043 shu

Construction of copper tetrakis(4-carboxyphenyl)porphyrin/silver nanowire composite electrode for flexible and transparent supercapacitors

State Key Laboratory of Flexible Electronics (LoFE) & Institute of Advanced Materials (IAM), School of Materials Science and Engineering, Nanjing University of Posts and Telecommunications, Nanjing 210023, China

Corresponding author: Cuie ZHAO, iamcezhao@njupt.edu.cn
Received Date: 10 February 2025
Revised Date: 7 May 2025

Figures(5)

A two-dimensional copper tetrakis(4-carboxyphenyl)porphyrin (Cu-TCPP, H₂TCPP=tetra(4-carboxyphenyl)porphyrin) nanosheet was synthesized via a one-step hydrothermal method, and a Cu-TCPP/AgNWs composite electrode was constructed through a spray coating process. The combination of Cu-TCPP and AgNWs facilitated rapid electron transfer, enhancing the electrochemical performance of flexible transparent supercapacitors (FTSCs). Experimental results showed that the Cu-TCPP/AgNWs-based FTSCs achieved a specific areal capacitance of 5.96 mF·cm^-2 with a transmittance of 58.6%. Furthermore, after 180° bending and folding, the capacitance retention remained as high as 87%, demonstrating excellent mechanical flexibility.
- transparent supercapacitors,
- conductive composite electrodes,
- spray coating,
- silver nanowires
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