Citation: Hongren RONG, Gexiang GAO, Zhiwei LIU, Ke ZHOU, Lixin SU, Hao HUANG, Wenlong LIU, Qi LIU. High-performance supercapacitor based on 1D cobalt-based coordination polymer[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(6): 1183-1195. doi: 10.11862/CJIC.20250034 shu

High-performance supercapacitor based on 1D cobalt-based coordination polymer

Hongren RONG ¹ ,
Gexiang GAO ¹ ,
Zhiwei LIU ¹ ,
Ke ZHOU ¹ ,
Lixin SU ¹ ,
Hao HUANG ¹ ,
Wenlong LIU ² ,
Qi LIU ^1,,

1.
Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering, Changzhou University, Changzhou, Jiangsu 213164, China
2.
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225009, China

Corresponding author: Qi LIU, liuqi62@163.com; liuqi@cczu.edu.cn
Received Date: 26 January 2025
Revised Date: 22 April 2025

Figures(6)

A low-cost 1D cobalt-based coordination polymer (CP) [Co(BGPD)(DMSO)₂(H₂O)₂] (Co-BD; H₂BGPD=N, N'-bis(glycinyl)pyromellitic diimide; DMSO=dimethyl sulfoxide) was synthesized by a simple method, and its crystal structure was characterized. In a three-electrode system, Co-BD, as the electrode material for supercapacitors, achieved a specific capacitance of 830 F·g^-1 at 1 A·g^-1, equivalent to a specific capacity of 116.4 mAh·g^-1, and exhibited high-rate capability, reaching 212 F·g^-1 at 20 A·g^-1. Impressively, Co-BD||rGO (reduced graphene oxide), representing an asymmetrical supercapacitor, owns a higher energy density of 14.2 Wh·kg^-1 at 0.80 kW·kg^-1, and an excellent cycle performance (After 4 000 cycles at 1 A·g^-1, the capacitance retention was up to 94%).
- supercapacitor,
- cobalt compound,
- coordination polymers,
- crystal structure,
- electrode materials,
- electrochemical performances
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沈阳化工大学材料科学与工程学院沈阳 110142