Citation: Wanting CHEN, Chufei MIAO, Yan LIU, Bobi ZHENG, Xiaoyu ZHENG, Han XU, Jumei TIAN. Syntheses, characterization, and luminescence properties of Yb(Ⅲ)-based one-dimensional chain coordination polymer[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(8): 1672-1680. doi: 10.11862/CJIC.20250013 shu

Syntheses, characterization, and luminescence properties of Yb(Ⅲ)-based one-dimensional chain coordination polymer

Wanting CHEN ^{1, #} ,
Chufei MIAO ^{1, #} ,
Yan LIU ¹ ,
Bobi ZHENG ¹ ,
Xiaoyu ZHENG ¹ ,
Han XU ² ,
Jumei TIAN ^1,,

1.
Engineering Research Center of Stomatological Biomaterials, Fujian Province University, School of Stomatology of Xiamen Medical College, Xiamen, Fujian 361023, China
2.
Yunnan Key Laboratory of Pharmacology for Natural Products, School of Pharmaceutical Science, Kunming Medical University, Kunming 650500, China

Corresponding author: Jumei TIAN, 201400010312@xmmc.edu.cn

Received Date: 11 January 2025
Revised Date: 24 May 2025

Figures(3)

One Yb(Ⅲ)-based coordination polymer, {[Yb(H₂dhtp)_1.5(H₂O)₄]·3H₂O}_n (1) (H₄dhtp=2, 5-dihydroxyterephthalic acid), was fabricated and structurally characterized by single-crystal X-ray diffraction, IR, powder X-ray diffraction, X-ray diffraction, and elemental analysis. Complex 1 displays a 1D chain structure, and belongs to P1 group. The solid-state luminescent spectrum of 1 showed an emission band with the maximum at 508 nm (λ_ex=408 nm). It exhibited the emission characteristic of the H₄dhtp ligand. The fluorescence of 1 in water displayed the strongest intensity. In detecting various metal ions, adding Zr⁴⁺ led to a blue shift in fluorescence, accompanied by an increase in intensity, whereas the presence of Fe³⁺ resulted in a decrease in luminescence. The changes observed in the IR spectrum indicate an interaction between Fe³⁺/Zr⁴⁺ and complex 1, resulting in the variation of luminescence properties.
- coordination polymers,
- structure,
- luminescence
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