Citation: Huirong BAO, Jun YANG, Xiaomiao FENG. Preparation and electrochemical properties of NiCoP/polypyrrole/carbon cloth by electrodeposition[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(6): 1083-1093. doi: 10.11862/CJIC.20250008 shu

Preparation and electrochemical properties of NiCoP/polypyrrole/carbon cloth by electrodeposition

1.
State Key Laboratory of Flexible Electronics (LoFE), Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications, Nanjing 210023, China
2.
Aerospace Newsky Technology Co., Ltd., Wuxi, Jiangsu 214062, China

Corresponding author: Xiaomiao FENG, iamxmfeng@njupt.edu.cn
Received Date: 7 January 2025
Revised Date: 21 April 2025

Figures(9)

The NiCoP/PPy/CC composite material composed of nickel-cobalt bimetallic phosphide (NiCoP) and polypyrrole (PPy) was constructed on the surface of carbon cloth (CC) by one-step electrodeposition, and the effect of the addition amount of pyrrole on the morphology, structure, and properties of the material was investigated. When the concentration of pyrrole was 3 mol·L^-1, the electrochemical performance of the NiCoP/PPy/CC-3 electrode was the best, with good electrochemical performance in a three-electrode system. At a current density of 4.0 mA·cm^-2, the area-specific capacitance of the electrode was 1 068.11 mF·cm^-2, and the corresponding mass-specific capacitance was 508.62 F·g^-1. After 6 000 cycles at a current density of 8.0 mA·cm^-2, the capacitance retention rate was 90.1%. The electrode was applied to a flexible asymmetric supercapacitor. The flexible device could achieve a 180° bending, and the initial specific capacitance of the device remained 88.6% after 10 000 cycles at a current density of 8.0 mA·cm^-2. In addition, two asymmetric supercapacitors in series can effectively light up a yellow light-emitting diode (LED).
- supercapacitor,
- transition metal phosphide,
- electrodeposition,
- polypyrrole,
- carbon cloth
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