Citation: Youbo HU, Donggang LI, Changhua SUN, Zhenzhong LU, Songjun GU. Coordination polymers based on anthracene- and pyrene-derived ligands: Crystal structure, fluorescent property, and framework isomerization[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(8): 1681-1688. doi: 10.11862/CJIC.20250004 shu

Coordination polymers based on anthracene- and pyrene-derived ligands: Crystal structure, fluorescent property, and framework isomerization

1.
Heilongjiang Provincial Institute of Quality Supervision and Testing, Harbin 150090, China
2.
School of Flexible Electronics (Future Technologies), Nanjing Tech University, Nanjing 211816, China

Corresponding author: Songjun GU, csking43@sina.com; chemzr@126.com
Received Date: 5 January 2025
Revised Date: 11 June 2025

Figures(6)

Six coordination polymers based on 9, 10-di(pyridine-4-yl)-anthracene (DPA) and 1, 6-di(1H-imidazol-1-yl)pyrene (DIP) were obtained by solvothermal reactions. {[Zn(DPA)Cl₂]·DMF·2H₂O}_n (1) and {[Zn_1.5(DPA)_1.5Cl₃]·5H₂O}_n (2) are framework isomers, which both contain zigzag chains formed by DPA, Zn²⁺, and Cl^-. The zigzag chains in 1 are further assembled by C—H…Cl interactions into layers, and these layers exhibit two different orientations, displaying a rare 2D to 3D interpenetration mode. The zigzag chains in 2 are parallelly arranged. {[Zn₃(DPA)₃Br₆]·2DMF·1.5H₂O}_n (3) is isostructural to 2. 3 was obtained using ZnBr₂ instead of ZnCl₂.[M(DPA) (formate)₂(H₂O)₂]_n[M=Co (4), Cu (5)] are isostructural, contain chain structures formed by DPA, Cu²⁺/Co²⁺, and formate ions, which were formed in situ in the solvothermal reaction. {[Zn(DIP)₂Cl]ClO₄}_n (6) contains a layer structure formed by DIP and Zn²⁺. Free DPA and DIP ligands exhibited high fluorescence at room temperature, and coordination polymers 3 and 6 displayed enhanced fluorescent emissions.
- coordination polymer,
- anthracene derivatives,
- pyrene derivatives,
- fluorescence,
- framework isomerization
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1.
沈阳化工大学材料科学与工程学院沈阳 110142