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Citation: Yu BAI, Jijiang WANG, Long TANG, Erlin YUE, Chao BAI, Xiao WANG, Yuqi ZHANG. A cadmium(Ⅱ) coordination polymer based on a semirigid tetracarboxylate ligand for highly selective detection of Fe3+ and 4-nitrophenol[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(6): 1217-1226. doi: 10.11862/CJIC.20240457 shu

A cadmium(Ⅱ) coordination polymer based on a semirigid tetracarboxylate ligand for highly selective detection of Fe3+ and 4-nitrophenol

  • Yan'an City Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China

  • Corresponding author: Jijiang WANG, yadxwjj@126.com
  • Received Date: 25 December 2024
    Revised Date: 5 April 2025

Figures(6)

  • A novel coordination polymer (CP) {[Cd2(L)(1,4-bimb)1.5(DMF)2]·DMF}n (1) (H4L=5, 5′-[1,1′-biphenyl-4,4′-diylbis(oxy)]diisophthalic acid, 1,4-bimb=1,4-bis(imidazole-1-ylmethyl)-benzene) has been designed and synthesized through solvothermal reaction. Structural analysis shows that Cd(Ⅱ) is connected by H4L and 1,4-bimb to form a 2D network, and 1,4-bimb further expands the 2D network into a 3D framework. CP 1 can be used as an excellent fluorescence sensor for Fe3+ and 4-nitrophenol (4-NP), with low detection limits and good anti-interference. The detection limits of Fe3+ and 4-NP were 0.034 and 0.031 μmol·L-1, respectively. In addition, the fluorescence quenching mechanism was studied. 1 was successfully applied to determine Fe3+ and 4-NP content in the Yanhe River water sample.
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