Citation: Yukun CHEN, Kexin FENG, Bolun ZHANG, Wentao SONG, Jianjun ZHANG. Syntheses, crystal structures, and diametrically opposed mechanically-stimulated luminescence response of two Mg(Ⅱ) metal-organic frameworks[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(6): 1227-1234. doi: 10.11862/CJIC.20240448 shu

Syntheses, crystal structures, and diametrically opposed mechanically-stimulated luminescence response of two Mg(Ⅱ) metal-organic frameworks

School of Chemistry, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: Jianjun ZHANG, zhangjj@dlut.edu.cn
Received Date: 20 December 2024
Revised Date: 5 April 2025

Figures(5)

The reaction of Mg²⁺ and 5-{1, 3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl}terephthalic acid (H₂L) leads to two metal-organic frameworks, [Mg(L)(DMF)₂(H₂O)₂]₂·5DMF·2H₂O (1) with a 1D structure and [Mg₂(L)₂(DMSO)₃(H₂O)] (2) with a 2D (4, 4)-net structure. Interestingly, the two compounds exhibit distinct luminescent responses to external mechanical stimuli. 1 exhibited exceptional resistance mechanical chromic luminescence (RMCL), which can be attributed to the predominant hydrogen bonds and the presence of high-boiling-point solvent molecules within its structure. 2 had a reversible MCL property, which can be attributed to the dominant π-π weak interactions, coupled with the reversible destruction/restoration of its crystallinity under grinding/fumigation.
- metal-organic framework,
- crystal structure,
- mechanical chromic luminescence,
- resistance mechanical chromic luminescence,
- weak interaction
1. [1]
  ZHOU Q, ZHANG X M, NING L J, SONG Y H, WANG Y L, FENG J K, GONG Q Y, HUANG Y J. Stimuli-chromic multi-component smart organic materials[J]. J. Mater. Chem. C, 2024,12(47):18991-19016. doi: 10.1039/D4TC04185B
2. [2]
  YIN Y, CHEN Z, LI R H, YI F, LIANG X C, CHENG S Q, WANG K, SUN Y, LIU Y. Highly emissive multipurpose organoplatinum(Ⅱ) metallacycles with contrasting mechanoresponsive features[J]. Inorg. Chem., 2022,61(6):2883-2891. doi: 10.1021/acs.inorgchem.1c03563
3. [3]
  NI J, WANG Y G, WANG H H, XU L, ZHAO Y Q, PAN Y Z, ZHANG J J. Thermo- and mechanical-grinding-triggered color and luminescence switches of the diimine-platinum(Ⅱ)) complex with 4-bromo-2, 2'-bipyridine[J]. Dalton Trans., 2014,43(1):352-360. doi: 10.1039/C3DT51936H
4. [4]
  HUANG J X, ZHAO H, ZHANG J J, ZHANG B L, NI J, SONG B, LI Y Q, LIU S Q, DUAN C Y. Diemissive dye@CP composites with full-spectrum tunable mechanoluminescence[J]. J. Mater. Chem. C, 2021,9(42):15165-15174. doi: 10.1039/D1TC02841C
5. [5]
  LI M Y, FANG W J, LIU S Q, NI J, ZHANG J J. Two new Zn(Ⅱ)/Cd(Ⅱ) one-dimensional coordination polymers based on naphthalimide dicarboxylic ligand[J]. Chin. J. Struct. Chem., 2019,38(10):1807-1813.
6. [6]
  WANG H Y, LIU S Q, FENG K X, ZHANG J J. Afterglow stimulation response behaviors of a benzimidazole derivative based on crystalline-to-crystalline transition[J]. Chinese J. Inorg. Chem., 2023,39(8):1571-1578.
7. [7]
  LI R F, CHEN X Y, ZHANG H, WANG Y R, LV Y, JIANG H P, GUO B W, FENG X. Co-based metal-organic framework nanosheets for robust hydrogen evolution in alkaline media[J]. Inorg. Chem., 2024,63(4):2282-2288. doi: 10.1021/acs.inorgchem.3c04291
8. [8]
  WU W W, CAI J J, LIANG X Y, LI Z Z, ANDRA S, GAO K, LUN H J, LI Y M. Anisotropic single-crystal proton conduction in a sodium chain-based coordination polymer[J]. ACS Appl. Mater. Interfaces, 2024,16(49):68358-68367. doi: 10.1021/acsami.4c15534
9. [9]
  SINGH D, BHATTACHARYYA P K, BARUAH J B. Structural studies on solvates of cyclic imide tethered carboxylic acids with pyridine and quinoline[J]. Cryst. Growth Des., 2010,10(1):348-356. doi: 10.1021/cg900938x
10. [10]
  SHELDRICK G M. SHELXT-integrated space-group and crystal-structure determination[J]. Acta Crystallogr. Sect. A, 2015,A71:3-8.
11. [11]
  FENG K X, WANG H Y, ZHANG P P, ZHANG J J, ZHANG W Q, WANG T, LIU S Q, NI J. Two calcium coordination polymers with multi-stimuli-responsive properties[J]. Eur J. Inorg. Chem., 2023,26(9)e202200686. doi: 10.1002/ejic.202200686
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